Article
Materials Science, Multidisciplinary
Dukhan Kim, Emily A. Mueller, Da Seul Yang, Danielle E. Fagnani, Jinsang Kim, Anne J. McNeil
Summary: This study demonstrates that a single copolymer containing a conjugated poly(3-hexylthiophene) backbone and fullerene-functionalized side chains can serve as a general blend stabilizer, suppressing phase separation in multiple conjugated polymer/fullerene thin film blends as well as in a photovoltaic device.
ACS APPLIED POLYMER MATERIALS
(2021)
Article
Materials Science, Multidisciplinary
Xuyu Gao, Ruitao Yu, Xiaochen Song, Xianwang Tao, Huabin Wang, Mengyuan Zhu, Yijing Wu, Yinming He, Youtian Tao
Summary: The incorporation of BODIPY units into polymer donor materials has been found to enhance the efficiency of polymer solar cells, particularly when nonfullerene acceptors are used. By altering morphology and improving light harvesting, utilizing terpolymer as electron donors can significantly boost the performance of polymer solar cells.
JOURNAL OF MATERIALS CHEMISTRY C
(2021)
Article
Polymer Science
Washat Ware, Tia Wright, Yimin Mao, Shubo Han, Jessa Guffie, Evgeny O. Danilov, Jeromy Rech, Wei You, Zhiping Luo, Bhoj Gautam
Summary: Research shows that tuning aggregation in polymer blends can optimize charge generation, which is beneficial for the design of highly efficient organic photovoltaic devices.
Article
Chemistry, Multidisciplinary
Yuqian Yang, Qiu Xiong, Jihuai Wu, Yongguang Tu, Tianxiao Sun, Guixiang Li, Xuping Liu, Xiaobing Wang, Yitian Du, Chunyan Deng, Lina Tan, Yuelin Wei, Yu Lin, Yunfang Huang, Miaoliang Huang, Weihai Sun, Leqing Fan, Yiming Xie, Jianming Lin, Zhang Lan, Valerio Stacchinii, Artem Musiienko, Qin Hu, Peng Gao, Antonio Abate, Mohammad Khaja Nazeeruddin
Summary: This study introduces a novel strategy of spinodal decomposition to create a poly(3-hexylthiophene)/perovskite (P3HT/PVK) heterointerface, effectively reducing energy and carrier losses in perovskite solar cells (PSCs). The P3HT/PVK heterointerface improves energy alignment, reducing energy loss at the interface, and the interpenetrating structure bridges a transport channel, decreasing carrier loss at the interface. This innovative approach achieves a remarkable power conversion efficiency of 24.53% for PSCs.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Chenyi Yang, Runnan Yu, Chenyu Liu, Hao Li, Shaoqing Zhang, Jianhui Hou
Summary: This study aimed to improve the performance of P3HT-based organic solar cells by using solid and solvent additives. The solid additive (SA4) resulted in a more ordered molecular packing and phase separation, leading to a higher power conversion efficiency (PCE) of over 10% for the first time in P3HT-based OSCs.
Article
Polymer Science
Morongwa E. Ramoroka, Siyabonga B. Mdluli, Vivian S. John-Denk, Kwena D. Modibane, Christopher J. Arendse, Emmanuel I. Iwuoha
Summary: This report focuses on the synthesis of a novel material, TTT-co-P3HT, as a donor material for organic solar cells. The synthesized TTT-co-P3HT showed potential with broader electrochemical and optical band-gaps compared to P3HT, but exhibited insufficient electron/hole separation and charge transfer. Ultimately, the devices using TTT-co-P3HT had a significantly lower power conversion efficiency than those using P3HT.
Article
Chemistry, Physical
Daehee Han, Geon-U Kim, Dongchan Lee, Chulhee Lim, Seungjin Lee, Dahyun Jeong, Shinuk Cho, Changyeon Lee, Bumjoon J. J. Kim
Summary: A new type of noncovalently fused polymer solar cell material has been developed, which enables high-efficiency fabrication. By controlling the molecular orientation of the material, high charge transport efficiency and low losses are achieved, leading to improved performance of the solar cell.
CHEMISTRY OF MATERIALS
(2023)
Review
Chemistry, Multidisciplinary
Lei Zhu, Ming Zhang, Wenkai Zhong, Shifeng Leng, Guanqing Zhou, Yecheng Zou, Xuan Su, Han Ding, Peiyang Gu, Feng Liu, Yongming Zhang
Summary: The article reviews the importance of non-fullerene acceptors (NFAs) in organic solar cells (OSCs) and the key steps and influencing factors for morphology optimization. It examines the morphological characteristics and recent research progress of pi-conjugated molecular systems based on IDT and Y6, as well as n-type pi-conjugated polymers, with special attention to high-performance Y6-based NFAs. The article aims to provide useful information and guidance for morphology optimization and achieving higher efficiency devices.
ENERGY & ENVIRONMENTAL SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Yuchen Yue, Bing Zheng, Wenjie Yang, Lijun Huo, Jingxia Wang, Lei Jiang
Summary: A facile and effective MAC strategy is reported for preparing high-quality blend films, which leads to all-PSCs with excellent optoelectronic properties and better stability. By controlling the meniscus advance speed, high-efficiency all-PSC devices can be fabricated.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Ziqi Liang, Jiangting He, Bin Zhao, Mengyuan Gao, Yu Chen, Long Ye, Miaomiao Li, Yanhou Geng
Summary: A polymer acceptor named IDTBTC8-CN was synthesized with improved miscibility with P3HT, and showed n-type charge transport characteristics. The blend film of P3HT:IDTBTC8-CN exhibited a champion efficiency of 8.30% in all-polymer solar cells, which is a new record for P3HT-based systems. The study implies the importance of molecular design of the polymer acceptors and morphology control for P3HT-based solar cells.
SCIENCE CHINA-CHEMISTRY
(2023)
Article
Chemistry, Physical
Tao Wang, Rui Sun, Yao Wu, Wei Wang, Meimei Zhang, Jie Min
Summary: This study demonstrates a promising design strategy to synthesize a polymer acceptor PT-YTz with intensified and extended absorption spectrum and enhanced electron mobility. The PM6/PT-YTz all-PSCs showed favorable active layer morphology and high efficiency.
CHEMISTRY OF MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
Xin Liang, Shuai Zhang, Yuanwei Wu, Jiuxing Wang, Chunpeng Yang, Aziz Saparbaev, Shuguang Wen, Xichang Bao
Summary: Device engineering and morphology control are effective ways to improve the photovoltaic performance of organic solar cells, leading to higher charge generation and transport efficiency, as well as inhibiting exciton recombination. The use of PBB-TSD:Y6 in the active layer with a LBL process shows higher efficiency compared to BHJ process.
ORGANIC ELECTRONICS
(2022)
Article
Chemistry, Physical
Hyewon Park, Hyeonjung Park, Hyungju Ahn, Wooseop Lee, Jinseok Park, Bumjoon J. Kim, Dong Ki Yoon
Summary: Nanoconfinement is an effective strategy to control the orientations and orderings of conjugated polymers (CPs). The study investigates the chain orientations of two crystal polymorphs, Form I and Form II, in poly(3dodecylthiophene)s (P3DDTs) using a porous anodic aluminum oxide (AAO) template. The results show that the pore diameter of the AAO template and the regioregularity (RR) of P3DDTs affect the orientational changes of Form I and Form II crystals, providing guidelines for achieving CPs with controlled intermolecular assembly and chain orientations.
CHEMISTRY OF MATERIALS
(2023)
Article
Energy & Fuels
Jing Song, Haibing Xie, Eng Liang Lim, Yahong Li, Tengfei Kong, Yang Zhang, Xia Zhou, Chunhui Duan, Dongqin Bi
Summary: The study demonstrated a multi-strategy approach to optimize CsPbI2Br perovskite solar cells, achieving high efficiency and long-term stability by enhancing phase stability and passivating film defects.
Article
Polymer Science
Mark Clyde Staub, Shichen Yu, Christopher Yuren Li
Summary: This study reports the fabrication of polymer crystalsomes formed by 1D polymer crystals. P3HT crystalsomes were successfully prepared using a miniemulsion solution crystallization method, and their properties were examined through microscopy and diffraction experiments. The results reveal curvature-dependent structural, thermal, and electro-optical properties of P3HT crystalsomes.
MACROMOLECULAR RAPID COMMUNICATIONS
(2023)
Article
Materials Science, Multidisciplinary
Katerina Skopalova, Itana Nusa Bubanja, Dragomir Stanisavljev, Nikola Cvjeticanin, Vera Kasparkova, Eliska Dad'ova, Erika Pavlikova, Marek Koutny, Marija Gizdavic-Nikolaidis, Petr Humpolicek
Summary: This study compares the biological properties of PANI prepared by different synthesis methods and oxidizing agents, which improves its potential applications in the biomedical field.
Article
Materials Science, Multidisciplinary
Hui-Ping Li, Cai-Yan Gao, Zhi-Ping Chen, Xin-Heng Fan, Lian-Ming Yang
Summary: In this study, a novel type of D-A non-fused-ring copolymers was designed and synthesized to overcome the trade-off relationship between electrical conductivity and Seebeck coefficient in organic semiconductors. The incorporation of fluorine atoms into the polymer backbone effectively increased the ordered degree of molecular stacking and improved both the electrical conductivity and Seebeck coefficient. The bimodal orientation of polymers played a crucial role in decoupling the correlation between electrical conductivity and Seebeck coefficient.
Article
Materials Science, Multidisciplinary
Mansour A. S. Salem, Amjad Mumtaz Khan, Hatem A. M. Saleh, Khalil M. A. Qasem, Mizna Ahmed, Aadil Shafi Bhat, Abdulaziz Abdullah Qasem Ali, Younes S. A. Ghanem, Ali Alrabie, Abdel-Basit Al-Odayni, Waseem Sharaf Saeed, Basheer Al-Anesi
Summary: This research focuses on the versatile substance, polyaniline/layered double hydroxide (PANI@Nd-Co/LDH), under solvothermal conditions. A thorough analysis of its structure and morphology was conducted using various analytical methods. The findings showed that PANI@Nd-Co/LDH exhibited highly sensitive and specific fluorescence detection of Pb(II) and Al(III), outperforming other heavy metal ions. The sensor demonstrated a turn-off fluorescence response for Pb(II) ions and a turn-on fluorescence response for Al(III) ions. The minimum detectable limits (MDL) were determined to be 9.6 nM for Pb(II) and 220 nM for Al(III). PANI@Nd-Co/LDH could be easily regenerated and reused for multiple cycles. The detection mechanisms involved the inner filter effect (IFE) for Pb(II) and the chelation-enhanced fluorescence (CHEF) effect for Al(III). These results highlight the excellent potential of PANI@Nd-Co/LDH in the detection and recognition of Pb(II) and Al(III) ions.