4.3 Article

Unexpected Reaction of Oximinoacetoacetate with Amines: A Novel Synthesis of Carbamates

Journal

SYNTHETIC COMMUNICATIONS
Volume 39, Issue 17, Pages 3010-3015

Publisher

TAYLOR & FRANCIS INC
DOI: 10.1080/00397910802564741

Keywords

Carbamate synthesis; keto-enol tautomerization; oxime

Funding

  1. Alexander von Humboldt Foundation

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The synthesis of alkyl carbamates by a solvent-free reaction of oximinoacetoacetate and amine at 130 degrees C is reported. A preliminary mechanism to this unexpected reaction is also given.

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