Journal
SYNTHESIS-STUTTGART
Volume 46, Issue 12, Pages 1573-1582Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0033-1341224
Keywords
prochiral dienone; phenol dearomatization; desymmetrization; enantioselective catalysis
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Funding
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- Canada Foundation for Innovation (CFI)
- provincial government of Quebec (FQRNT)
- provincial government of Quebec (CCVC)
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This article describes a number of catalytic methods for enantioselectively desymmetrizing prochiral dienone systems. The core structures obtained using these methodologies appear in several bioactive natural products, and the processes appear to be effective tools for producing key intermediates in the synthesis of complex structures.
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