4.5 Article

N-Heterocyclic Carbene Catalyzed Hydrophosphonylation of Aldehydes

Journal

SYNTHESIS-STUTTGART
Volume -, Issue 13, Pages 2073-2078

Publisher

GEORG THIEME VERLAG KG
DOI: 10.1055/s-0030-1260045

Keywords

N-heterocyclic carbene; Pudovik-type reaction; alpha-hydroxyphosphonates; aldehydes; C-P bond

Funding

  1. Start-Up Foundation for Young Scientists of Shi He Zi University [RCZX200806]

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N-Heterocyclic carbene catalyzed Pudovik-type reaction of dimethyl trimethylsilyl phosphite and aldehydes for the construction of carbon-phosphorus bonds have been developed, providing alpha-hydroxyphosphonates in moderate to excellent yield.

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