Journal
SYNTHESIS-STUTTGART
Volume -, Issue 20, Pages 3493-3503Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0030-1258226
Keywords
antibiotics; diastereoselectivity; phenols; terpenoids; oxidation
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Funding
- Regional Government of Andalucia [P07-FQM-03101, FQM-348]
- Spanish Agency for the International Development and Cooperation (AECID)
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A series of 12-hydroxy-substituted abietane diterpenes, functionalized on C19 or C18, have been synthesized starting from 18-hydroxyferruginol. The first synthesis of antibacterial hanagokenol A and fortunins E, G, and H, and a new procedure for preparing sugikurojin A and the immunosuppressive 19-hydroxyferruginol are reported.
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