Article
Electrochemistry
Muhammad Ameerullah Sahudin, Ling Ling Tan, Mohd Sukor Su'ait, Nurul Huda Abd Karim, Mukram Mohamad Mackeen
Summary: An impedimetric sensor was developed for sensitive and selective determination of histamine in foods, with high recovery ability. The sensor showed high selectivity towards histamine and can accurately measure histamine levels in food samples, with features of high throughput and reusability.
ELECTROCHIMICA ACTA
(2021)
Article
Chemistry, Applied
Renan C. Silva, Felipe S. M. Canisares, Alessandra M. G. Mutti, Ana M. Pires, Sergio A. M. Lima
Summary: The development of pH sensors is essential for distinguishing different pHs in various applications. In this study, we synthesized eight pH-sensitive small Schiff bases and tested their photophysical properties. We found that these Schiff bases exhibit similar behavior as pH sensors in the range of pH 3.0-12.0, making them suitable for colorimetric and fluorometric detection.
Article
Chemistry, Physical
Mingyi Kang, Dan Zhang, Yuanying Liu, Kehui Wei, Peng Liu, Manman Shi, Xiaofeng Yang, Meishan Pei, Guangyou Zhang
Summary: A new fluorescent probe, EQTPC[Ga3+], was designed and synthesized for detection of chromium(III) and rhodium(III). The probe exhibited turn-on fluorescent response towards Ga3+, and further turn-off response for Rh3+ and Cr3+. The optical activity of EQTPC[Ga3+]-Cr3+ was reversible when treated with EDTA. The detection limits were 6.08 x 10(-8) M, 9.72 x 10(-8) M, and 1.27 x 10(-8) M for Ga3+, Rh3+, and Cr3+ respectively.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2023)
Article
Biochemistry & Molecular Biology
Danielle O. Maia, Valdenice F. Santos, Cristina R. S. Barbosa, Yuri N. Froes, Debora F. Muniz, Ana L. E. Santos, Maria H. C. Santos, Romerio R. S. Silva, Claudio G. L. Silva, Racquel O. S. Souza, Joicy C. S. Sousa, Henrique D. M. Coutinho, Claudener S. Teixeira
Summary: The schiff base complex [Ni(L2)] showed moderate toxicity, significant leishmanicidal activity, and antibacterial effects against P. aeruginosa, but did not have clinically relevant minimum inhibitory concentration against S. aureus and E. coli. The combination of [Ni(L2)] complex with antibacterial drugs enhanced the antibiotic activity against multi-resistant strains, suggesting its potential as a promising molecule for new therapies against resistant bacteria and leishmaniasis.
CHEMICO-BIOLOGICAL INTERACTIONS
(2022)
Article
Chemistry, Organic
Maciej Skrodzki, Violetta Patroniak, Piotr Pawluc
Summary: A bench-stable cobalt(II) complex, with a 3N-donor socket-type benzimidazole-imine-2H-imidazole ligand, is reported as an efficient precatalyst for regioselective hydrosilylation of terminal alkynes, providing high yields with excellent selectivity. This catalyst loading range of 0.5-0.05 mol % is among the most efficient reported for cobalt-catalyzed alkyne hydrosilylation in the literature.
Article
Chemistry, Physical
Pragyan P. Dash, P. Mohanty, R. Behura, S. Behera, P. Singla, Subash C. Sahoo, Suban K. Sahoo, Bigyan R. Jali
Summary: In this study, a readily prepared anthracene-based Schiff base L was synthesized and characterized. The receptor L exhibited weak emission in DMSO, but showed significant enhancement upon the addition of trace amounts of water. The water sensing mechanism of L was investigated using various techniques, and it was found that the L-H2O complex formation is reversible upon the addition of DMSO. The sensor L was successfully applied for moisture detection in different raw food components.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2023)
Article
Energy & Fuels
Yajuan Wang, Wenqiang Liu, Juan Zhang, Qingwen Shan
Summary: Twelve schiff base metal complexes were synthesized and studied for their application in adsorption desulfurization. The schiff base metal complex of melamine and cobalt showed the best adsorption performance. Characterization and analysis of the complex revealed a maximum adsorption capacity of 21.66 mg/g for DBT, and the adsorption capacity remained stable even after being reused for 5 times. The adsorption process followed the Freundlich adsorption isothermal model and the pseudo-second-order model kinetics. In addition, the adsorbent demonstrated different removal efficiencies for various sulfides, with dibenzothiophene showing the highest removal efficiency.
Article
Materials Science, Multidisciplinary
Dario M. Gonzalez, Loreto A. Hernandez, Jocelyn Oyarce, Andrea Alfaro, Nestor Novoa, Jonathan Cisterna, Ivan Brito, David Carrillo, Carolina Manzur
Summary: In this study, a mono-anionic complex C1 was synthesized by a reaction between cobalt (II) acetate tetrahydrate and a new ONO-tridentate Schiff base ligand containing a thiophenyl group. The resulting metallopolymer deposit from electropolymerization of C1 on FTO electrodes served as an efficient glucose sensor with a linear amperometric response and low limits of detection and quantification. The electrochemical sensor showed excellent reproducibility in manufacturing process, stability under environmental conditions, and consistent measurements over a two-week period.
Article
Chemistry, Inorganic & Nuclear
Dinesh Maity, Sibshankar Bari, Pritam Ghosh, Partha Roy
Summary: The new Schiff-base molecule H4LCl serves as a colorimetric and fluorescent pH probe, with fluorescence intensity and quantum yield increasing as pH of the medium increases. The pKa value is 7.18, with intensity enhancement occurring via an ICT-AIE controlled pathway, and naked eye detection is possible by noting color changes.
INORGANIC CHEMISTRY COMMUNICATIONS
(2022)
Article
Chemistry, Multidisciplinary
Hao Sun, Yan Jiang, Jing Nie, Jianhua Wei, Baoxi Miao, Yun Zhao, Lifang Zhang, Zhonghai Ni
Summary: Organic fluorescent materials with multifunctional properties have been designed and synthesized, showing dramatic absorption/fluorescence dual-mode color changes induced by water and zinc ions. These materials have been applied in the development of eco-friendly inkless rewritable paper and high-sensitivity Zn2+ ion sensors for living cells. The strategy presented in this study provides a reference for developing multifunctional materials with wider applications.
MATERIALS CHEMISTRY FRONTIERS
(2021)
Article
Chemistry, Applied
Kajal Bamnavat, Vinita Bhardwaj, Thangaraj Anand, S. K. Ashok Kumar, Suban K. Sahoo
Summary: pH determination is crucial in various biological and chemical processes. The manuscript explores the use of a pyridoxal derived Schiff base L for fluorescent pH sensing. Through the formation of self-aggregates and fluorescence analysis, the compound showed potential for pH detection in different ranges.
Article
Spectroscopy
Masoumeh Saremi, Ali Kakanejadifard, Motaleb Ghasemian, Mohsen Adeli
Summary: A novel Schiff base-based sensor (L) has been designed, synthesized, and developed as a fluorescent and colorimetric sensor for cyanide and acetate. This sensor displayed a quick response and rapid sensitivity to CN- and AcO-, with a remarkable color change from yellow to red that could be detected by the naked eyes. It also showed fluorescence enhancement when sensing CN- and AcO-. The results were supported by UV-Vis studies, 1H NMR titration, and theoretical DFT calculations.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2023)
Article
Spectroscopy
Arul Pundi, Jemkun Chen, Chi-Jung Chang, Shih-Rong Hsieh, Ming-Ching Lee, Chun-Hung Chou, Tzong-Der Way
Summary: A new efficient Schiff base sensor, SB3, has been developed for fluorescent and colorimetric naked-eye turn-on sensing of cyanide anion (CN-) with high sensitivity and selectivity. SB3 interrupts intramolecular charge transfer to achieve high specificity towards CN-, resulting in remarkable color change and green fluorescence emission.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2021)
Article
Biochemistry & Molecular Biology
Chaoqiang Huang, Haiyan Liao, Xuhong Liu, Min Xiao, Songyi Liao, Sheng Gong, Fujie Yang, Xugang Shu, Xinhua Zhou
Summary: In this study, a novel sustained release system (VCSB-Zn(II)) was developed to enhance the utilization of zinc trace elements. VCSB exhibited superior chelation capacity for Zn2+ compared to chitosan, with a chelation capacity 1.7 times higher at 50.96 mg/g. The system demonstrated excellent sustained release performance in simulated gastric fluid, reaching a cumulative release rate of 77.81% with higher C=N content. This zinc sustained release system shows promising potential for trace element supplementation in animals.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2022)
Article
Engineering, Environmental
Zhimin Gong, Li Qian, Shuai Shao, Bo Fan, Jianbiao Peng, Kun Lu, Shixiang Gao
Summary: Solvent composition plays a crucial role in the synthesis of metal complex materials. In this study, a unique Schiff base Cu complex catalyst was designed and the effect of adding H2O during the synthesis process on the catalyst's catalytic performance was investigated. The results showed that adding a small amount of H2O significantly enhanced the catalyst's catalytic ability and improved the removal of the pollutant Methyl-paraben.
CHEMICAL ENGINEERING JOURNAL
(2022)