Journal
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY
Volume 42, Issue 3, Pages 336-344Publisher
TAYLOR & FRANCIS INC
DOI: 10.1080/15533174.2011.610770
Keywords
imidazole dicarboxylate; structures; thermal properties; transition metal
Funding
- National Natural Science Foundation of China [21071127, 20501017, J0830412]
- Natural Science Foundation of Henan Educational Committee [2009A150028, 2011A150029]
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Four complexes, [Cd(H2PIDC)(2)(2,2'-bipy)] (1), [Ni(H2PIDC)(2) (H2O)(2)]center dot 4H(2)O (2), [Co(H2PIDC)(2)(H2O)(2)] (3), and [Mn(H2PIDC)(2)(H2O)(2)] (4) have been hydro(solvo)thermally synthesized by reactions of 2-propyl-1H-imidazole-4,5-dicarboxylic acid (H3PIDC) with Cd(II), Ni(II), Co(II), and Mn(II) ions, respectively. Their crystal structures have been characterized by single X-ray determination. The thermal properties of the four complexes have been determined as well.
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