☆ 3.9 Article

A Novel Molecular Cubic Perovskite Built From Charge-Assisted Hydrogen Bond Linkages

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY (2011)

Journal

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY

Volume 41, Issue 9, Pages 1091-1094

Publisher

TAYLOR & FRANCIS INC

DOI: 10.1080/15533174.2011.591351

Keywords

crystal structure; hydrogen bonding; hydrothermal synthesis; molecular perovskite

Categories

Chemistry, Inorganic & Nuclear Nanoscience & Nanotechnology

Funding

National Natural Science Foundation of China [20971064, 21071074]
Foundation of Education Committee of Henan Province [092102210315]

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Abstract

A novel molecular cubic perovskite (C6H14N2)(NH4)[BF4](3), space group Pa-3 (number 205), has been hydrothermally synthesized and further characterized by x-ray diffraction studies, elemental analysis, infrared spectrum, and thermogravimetric analysis. This is the Gfirst molecular cubic perovskite based on the three-dimensional (3-D) array of complex C6H14N22+ (C6H14N2 = doubly protonated 1,4-diazabicyclo[2.2.2]octane), NH4+, and BF4- modular groups that are held together largely by the extensive hydrogen bonding. This work demonstrates that the perovskite-type structure is highly flexible to diverse chemical components and can be stabilized by a wide range of chemical interactions.

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