Journal
SYNLETT
Volume 25, Issue 5, Pages 645-652Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0033-1340501
Keywords
supported catalysis; palladium; cross-coupling; dendrimers; thiols
Categories
Funding
- Center of Excellence of Chemistry
- Research Council of the University of Isfahan
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A wide variety of diaryl sulfides has been synthesized in excellent yields via C-S cross-couplings of aryl/heteroaryl halides with aromatic/heteroaromatic thiols in the presence of palladium nanoparticles immobilized on nanosilica triazine dendritic polymer (Pd-np-nSTDP) as a reusable catalyst under thermal conditions and microwave irradiation. Pd-np-nSTDP also showed excellent catalytic activity for the preparation of a series of di- and trisulfides with benzene, pyridine, pyrimidine, and/or 1,3,5-triazine as the central cores by one-pot multi C-S cross-coupling reactions.
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