Journal
SYNLETT
Volume 24, Issue 17, Pages 2310-2314Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0033-1339861
Keywords
propargylic carbonates; allenylpalladium; phenanthrene derivatives; cyclization; -H elimination
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Funding
- National Basic Research Program of China [2011CB808700]
- National Natural Science Foundation of China [21232006]
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Under the catalysis of palladium acetate, 1,2-allenyl-palladium formed from propargylic carbonates may react with two molecules of benzyne to afford phenanthrene derivatives by cyclization and beta-H elimination.
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