4.4 Article

Functionalization of Single-Walled Carbon Nanotubes through 1,3-Cycloaddition of Carbonyl Ylides under Microwave Irradiation

Journal

SYNLETT
Volume -, Issue 10, Pages 1459-1462

Publisher

GEORG THIEME VERLAG KG
DOI: 10.1055/s-0031-1290681

Keywords

carbon nanotubes; microwave; epoxides; cycloadditions; solvent-free reactions

Funding

  1. MIUR

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The solvent-free, microwave-assisted 1,3-dipolar cycloaddition of carbonyl ylides, generated from a series of oxiranes, to SWCNTs (single-walled carbon nanotubes) is described. The procedure is extremely fast and repeatable. The reaction of SWCNTs with benzylidenmalononitrile epoxide afforded a gem-dicyano derivative that is well-suited to further transformation into esters or amides through the Pinner reaction.

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