Journal
SYNLETT
Volume -, Issue 9, Pages 1265-1267Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0030-1260541
Keywords
phosphonium salt; Bronsted acid; aza-Michael addition; propargyl amine; asymmetric synthesis
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Funding
- Nagoya University
- JSPS for Scientific Research
- Mitsubishi Foundation
- Funding Program for Next Generation World-Leading Researchers
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Enantioselective aza-Michael addition to conjugated nitroenynes has been developed. P-Spiro heterochiral arylaminophosphonium barfate 1b.BArF effectively catalyzes the reaction, and the corresponding conjugate adducts, beta-amino homopropargylic nitro compounds, are obtained in good chemical yields with high enantioselectivities.
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