4.4 Article

Radical Alkylations of Alkyl Halides and Unactivated C-H Bonds Using Vinyl Triflates

Journal

SYNLETT
Volume -, Issue 11, Pages 1647-1650

Publisher

GEORG THIEME VERLAG KG
DOI: 10.1055/s-0029-1219960

Keywords

alkylation; radical reaction; ketone; vinyl triflate

Funding

  1. Center for Molecular Design and Synthesis at KAIST
  2. Nanyang Technological University

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Radical alkylations of activated alkyl iodides and bromides were achieved using vinyl triflates in the presence of hexadimethyltin, whereas those of unactivated C-H bonds using vinyl triflates proceeded cleanly under tin-free conditions.

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