Journal
SYNLETT
Volume -, Issue 11, Pages 1661-1664Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2008-1078495
Keywords
organocatalysis; Mannich reaction; imines; asymmetric catalysis; isomerizations
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Funding
- JSPS [17350042]
- Japan Society
- Grants-in-Aid for Scientific Research [17350042] Funding Source: KAKEN
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An enantioselective direct Mannich reaction of acetylacetone with enecarbamates via protonation by a chiral monophosphoric acid catalyst is achieved, demonstrating the utility of in situ generation of unstable aliphatic imines.
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