Journal
SURFACE SCIENCE
Volume 630, Issue -, Pages 229-235Publisher
ELSEVIER
DOI: 10.1016/j.susc.2014.08.021
Keywords
HESXRD; SXRD; Pd; PdO; CO oxidation; Heterogeneous catalysis
Categories
Funding
- Swedish Research Council [349-2011-6491]
- Swedish Foundation for Strategic Research (SSF) [RMA06-0085]
- Crafoord foundation [20130825]
- Knut and Alice Wallenberg foundation [2003.0217]
- Anna and Edwin Berger foundation
- BMBF [05K10PS1 NanoXcat]
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We have performed a quantitative structure determination of the (root 5 x root 5) R27 degrees surface oxide, formed on Pd(100) under semi-realistic conditions for catalytic CO oxidation, using in situ high-energy surface X-ray diffraction. We describe the experiment and the extraction of quantitative data in detail. The structural results are in agreement with previous reports of a system consisting of a single layer of PdO(101) formed in pure O-2 on top of Pd(100) and studied under ultra-high vacuum conditions. (C) 2014 The Authors. Published by Elsevier B.V.
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