4.3 Article

Novel aroylhydrazine-amide derivatives bearing pyridine core: synthesis, characterisations and selective colorimetric recognition properties

Journal

SUPRAMOLECULAR CHEMISTRY
Volume 25, Issue 6, Pages 384-392

Publisher

TAYLOR & FRANCIS LTD
DOI: 10.1080/10610278.2013.783919

Keywords

aroylhydrazine-amide; anion recognition; colorimetric sensor; naked-eye

Funding

  1. National Natural Science Foundation of China [31101467]
  2. National Undergraduate Innovational Experimentation Programme [201210504018]
  3. Huazhong Agricultural University Scientific & Technological Self-innovation Foundation [2011SC07]
  4. Fundamental Research Funds for the Central Universities [2011PY086]

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Four aroylhydrazine-amides receptors AR1-4 with a hydrazine spacer have been designed, synthesised and characterised as novel colorimetric chemosensors by typical spectroscopic techniques. The receptors AR1-3 exhibited certainly selectivity and sensitivity towards F- and AcO-, forming 1:1 stoichiometry complex by hydrogen-bond interaction. Furthermore, AR4 has especially shown obvious colour change in the presence of these two important biologically anions.

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