4.5 Article

Effect of iron loading on the photocatalytic performance of Bi2WO6 photocatalyst

Journal

SUPERLATTICES AND MICROSTRUCTURES
Volume 76, Issue -, Pages 362-375

Publisher

ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
DOI: 10.1016/j.spmi.2014.10.014

Keywords

Bi2WO6; Hydrothermal method; Metal loading; Methylene blue; Photocatalytic activity

Funding

  1. Thailand Office of the Higher Education Commission through the National Research University (NRU) Project for Chiang Mai University
  2. Centre of Excellence in Materials Science
  3. Department of Chemistry and Department of Physics and Materials Science, Faculty of Science, Chiang Mai University
  4. National Research Council of Thailand

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Pure Bi2WO6 and nominal 0.1-2.0 mol% Fe-loaded Bi2WO6 samples were synthesized by hydrothermal method. All samples were characterized in order to obtain the correlation between structure and photocatalytic properties by X-ray diffraction, UV-vis diffuse reflectance spectrophotometry, Brunauer, Emmett and Teller-specific surface area, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, photoluminescence spectroscopy and inductively coupled plasma-optical emission spectroscopy. Photocatalytic activities of all photocatalyst samples were examined by studying the degradation of methylene blue under visible light irradiation. The 0.5 mol% Fe-loaded Bi2WO6 had the best activity in photodegradation of MB in aqueous solution under visible light irradiation. The high performance of Fe-loaded Bi2WO6 could be attributed to the fact that the Fe ions could act as electron traps promoting the electron-hole separation then enhancing the photocatalytic reaction. (C) 2014 Elsevier Ltd. All rights reserved.

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