Journal
SUPERCONDUCTOR SCIENCE & TECHNOLOGY
Volume 24, Issue 11, Pages -Publisher
IOP PUBLISHING LTD
DOI: 10.1088/0953-2048/24/11/115007
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Funding
- National Science Council of Taiwan [C-98-2112-M-213-006-MY3, NSC-099-2112-M-001-036-MY3]
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The microscopic effects of V doping in LiTi2O4 have been poorly understood. The present study employs x-ray absorption near-edge structure (XANES) and resonant inelastic soft-x-ray scattering (RIXS) spectroscopy to understand the change in the electronic structure due to dilute V doping in spinel LiTi2O4 and the possible origin for the rapid suppression of superconductivity in these compounds. Results from the XANES spectra at Ti L and K edges and Ti L-RIXS show that Ti exists in a mixed-valence state and, with V doping, the unoccupied states of Ti in the t(2g) band increase. The rapid suppression of superconductivity is associated with the change in Ti 3d electrons and Ti-O hybridization.
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