Journal
CHEMPLUSCHEM
Volume 80, Issue 5, Pages 820-826Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cplu.201402415
Keywords
ionic liquids; iron; nanostructures; Schiff bases; supported catalysts
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Funding
- Yasouj University
- Iran National Science Foundation (INSF)
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A novel iron-containing Schiff base and ionic liquid based bifunctional periodic mesoporous organosilica (Fe@SBIL-BPMO) was prepared, characterized, and its catalytic application was developed. The SBIL-BPMO was first prepared by the grafting of 3-aminopropyltrimethoxysilane on an ionic-liquid-based PMO followed by treatment with 2-hydroxybenzaldehyde in toluene at reflux. This material was then reacted with Fe(NO3)(3)9H(2)O to afford the Fe@BPMO-SBIL nanocatalyst. The catalyst was characterized by thermogravimetric analysis, nitrogen sorption experiments, diffuse reflectance FTIR spectroscopy, low-angle powder XRD, and TEM. The Fe@SBIL-BPMO catalyst was successfully applied in the one-pot synthesis of 3,4-dihydropyrimidinone/thione derivatives under solvent-free reactions. The stability, reactivity, and reusability of the catalyst under the reaction conditions have also been investigated.
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