4.7 Article

Chemical composition of particles from traditional burning of Pakistani wood species

Journal

ATMOSPHERIC ENVIRONMENT
Volume 121, Issue -, Pages 35-41

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.atmosenv.2015.01.041

Keywords

Wood smoke; Levoglucosan; Elemental and organic carbon; Biomass combustion

Funding

  1. Higher Education Commission (HEC), Pakistan
  2. Austrian Exchange Service (OEAD)
  3. European Union - European Social Fund [P-MR-09/1]

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Total particulate matter (TPM) emitted during burning of three types of Pakistani wood (eucalyptus camaldulensis, local name Safeeda; acacia nilotica, local name Kikar, Babul; dalbergia sissoo, Shisham, Tali) in a traditional brick stove were collected and analyzed for anhydrosugars, sugar alcohols, trace metals, soluble ions and carbonaceous species. This is a first study reporting anhydrosugars in wood smoke particles emitted during traditional burning of common wood types in Pakistan. Carbonaceous species showed the highest contribution to the particulate matter. Although the total carbon (TC) contribution was similar for all burnings (64.8-70.2%), the EC/OC ratio varied significantly, from 0.2 to 0.3 for Accacia and Dalbergia to 0.7-0.8 for Eucalyptus and Wood-mix. Among inorganic constituents potassium chloride and silicon were found at levels higher than 1%. The levoglucosan concentrations ranged from 3.0 to 6.6% (average 5.6%) with the highest value for Accacia and lowest value for the wood-mix. The high levoglucosan/mannosan ratios of 20-28 were typical for hardwood. The ratio between levoglucosan and galactosan varied stronger and was found to be around 13-20 for Accacia, Eucalyptus and Wood mix, and 43 for Dalbergia. The determined levoglucosan concentrations allowed assessing the conversion factor for calculation of biomass smoke contribution to ambient particulate matter levels in Pakistan. (C) 2015 Elsevier Ltd. All rights reserved.

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