4.3 Article

Synthesis of soluble N-functionalized polysaccharide derivatives using phenyl carbonate precursor and their application as catalysts

Journal

STARCH-STARKE
Volume 63, Issue 12, Pages 780-791

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/star.201100064

Keywords

Cellulose; Knoevenagel condensation; N-Functionalized polysaccharides; Polysaccharide phenyl carbonate; Starch

Funding

  1. Sharif University of Technology

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Soluble N-functionalized basic and cationic polysaccharides have been synthesized using polysaccharide phenyl carbonate as a precursor. The products and intermediates were thoroughly characterized by conventional methods. The quaternization of amino intermediates in various conditions was studied. Moreover, the potential of basic polymers as green and selective catalysts in Knoevenagel reaction was investigated. In all cases, only one isomer was obtained.

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