Influence of annealing temperature on structural, optical and magnetic properties of Zn0.95Cu0.02Cr0.03O powders

Zn0.95Cu0.02Cr0.03O powders have been synthesized by the sol-gel method and sintered in argon atmosphere under different temperatures. The structural, optical and magnetic properties of the powders were investigated by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), photoluminescence (PL) and vibrating sample magnetometer (VSM). The XRD results demonstrated that Cr and Cu ions are incorporated into ZnO successfully when annealing temperatures were 600 and 700 degrees C. But when the samples were annealed at 500 degrees C, the crystallinity of the samples was not very good. However, when the annealing temperature was increased to 800 degrees C, the secondary phase of Cu and ZnCr2O4 appeared in the samples. The PL spectra revealed that the position of the ultraviolet (UV) emission peak of the samples showed a blue shift and the green emission peak enhanced significantly with the annealing temperature increasing from 600 to 700 degrees C. Magnetic measurements indicated that the room temperature ferromagnetism of Zn0.95Cu0.02Cr0.03O was intrinsic in nature. In addition, the saturation magnetization (Ms) increased from 0.0078 to 0.0088 emuig with the annealing temperature increased from 600 to 700 degrees C. (C) 2011 Elsevier Ltd. All rights reserved.