4.7 Article

High efficiency and stable hydrogenated amorphous silicon radial junction solar cells built on VLS-grown silicon nanowires

Journal

SOLAR ENERGY MATERIALS AND SOLAR CELLS
Volume 118, Issue -, Pages 90-95

Publisher

ELSEVIER
DOI: 10.1016/j.solmat.2013.07.036

Keywords

Solar cell; Radial junction; Silicon nanowires; VLS method

Ask authors/readers for more resources

Hydrogenated amorphous silicon (a-Si:H) radial junction solar cells, built over a dense matrix of Si nanowires (SiNWs), benefit from strong light trapping. This allows the use of a very thin absorber layer without sacrificing the solar cell performance, while improving its stability. By optimizing the density of SiNWs grown via a plasma-assisted vapor-liquid-solid process on glass, we have achieved radial junction a-Si:H solar cells with an open circuit voltage of 0.80 V, short circuit current density of 16.1 mA/cm(2) and a high power conversion efficiency of 8.14%. Furthermore, we present experimental evidence of the excellent stability of such radial junction a-Si:H solar cells with a light-induced degradation of only similar to 6%, compared to the typical degradation of 15% to 20% in planar cells. These results indicate the feasible and promising approach towards a new generation of stable and high performance a-Si:H thin film solar cells. (C) 2013 Elsevier B.V. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Energy & Fuels

Nanostructured back reflectors produced using polystyrene assisted lithography for enhanced light trapping in silicon thin film solar cells

Zeyu Li, E. Rusli, Martin Foldyna, Junkang Wang, Wanghua Chen, Ari Bimo Prakoso, Chenjin Lu, Pere Roca i Cabarrocas

SOLAR ENERGY (2018)

Article Materials Science, Multidisciplinary

Toward Efficient Radial Junction Silicon Nanowire-Based Solar Mini-Modules

Mutaz Al-Ghzaiwat, Antonino Foti, Andre Nuesslein, Lukas Halagacka, Jacques Meot, Anne Labouret, Razvigor Ossikovski, Pere Roca i Cabarrocas, Martin Foldyna

PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS (2019)

Article Multidisciplinary Sciences

Low-cost high-efficiency system for solar-driven conversion of CO2 to hydrocarbons

Tran Ngoc Huan, Daniel Alves Dalla Corte, Sarah Lamaison, Dilan Karapinar, Lukas Lutz, Nicolas Menguy, Martin Foldyna, Silver-Hamill Turren-Cruz, Anders Hagfeldt, Federico Bella, Marc Fontecave, Victor Mougel

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2019)

Article Nanoscience & Nanotechnology

ALD of ZnO:Ti: Growth Mechanism and Application as an Efficient Transparent Conductive Oxide in Silicon Nanowire Solar Cells

Damien Coutancier, Shan-Ting Zhang, Simone Bernardini, Olivier Fournier, Tiphaine Mathieu-Pennober, Frederique Donsanti, Maria Tchernycheva, Martin Foldyna, Nathanaelle Schneider

ACS APPLIED MATERIALS & INTERFACES (2020)

Article Nanoscience & Nanotechnology

Improvement of carrier collection in Si/a-Si:H nanowire solar cells by using hybrid ITO/silver nanowires contacts

Tiphaine Mathieu-Pennober, Martin Foldyna, Shan-Ting Zhang, Francois H. Julien, Nathanaelle Schneider, Maria Tchernycheva

NANOTECHNOLOGY (2020)

Article Chemistry, Physical

Liquid-Assisted Vapor-Solid-Solid Silicon Nanowire Growth Mechanism Revealed by In Situ TEM When Using Cu-Sn Bimetallic Catalysts

Eric Ngo, Weixi Wang, Pavel Bulkin, Ileana Florea, Martin Foldyna, Pere Roca i Cabarrocas, Jean-Luc Maurice

Summary: This study introduces a silicon nanowire growth method using a dual-phase catalyst of liquid Sn and solid Cu3Si, resulting in a liquid-assisted VSS mechanism. The growth process is observed in situ at atomic resolution. The structural properties of the Si nanowires, such as growth direction and twin density, can be controlled by adjusting the Sn/Cu ratio.

JOURNAL OF PHYSICAL CHEMISTRY C (2021)

Article Optics

Tin reduction from fluorine doped tin oxide for silicon nanowire-based solar energy harvesting and storage

Halagacka Lukas, Gelnarova Zuzana, Al-Ghzaiwat Mutaz, Florea Ileana, Hornicek Jiri, Postava Kamil, Foldyna Martin

Summary: Hydrogen plasma reduction of fluorine doped tin oxide is a beneficial method to form tin nanodroplets directly on the surface, crucial for growth of silicon nanowires for solar cell technology. An original optical model accurately traces the formation process and barrier properties, allowing for real-time monitoring of tin reduction and nanowire growth. The approach is important for in situ monitoring of fabrication processes for radial junction devices.

OPTICS EXPRESS (2021)

Article Materials Science, Multidisciplinary

Room Temperature Growth of Silica Nanowires on Top of Ultrathin Si Nanowires Synthesized with Sn-Cu Bimetallic Seeds

Weixi Wang, Eric Ngo, Ileana Florea, Martin Foldyna, Pere Roca Cabarrocas, Jean-Luc Maurice

Summary: Si nanowires (NWs) are grown using Cu-Sn bimetallic catalysts in a plasma-enhanced chemical vapor deposition (PECVD) reactor, resulting in the formation of an amorphous SiO2 region on top of each crystalline SiNW. A new silica NW structure is observed in SiNWs with a diameter below 10 nm. The microstructure appears to be the result of a Si oxidation mechanism catalyzed by Cu3Si, which can be completely suppressed by depositing a protecting 2 nm thick layer of hydrogenated amorphous Si after SiNW growth. This study provides a reference for future applications based on Cu-Sn-catalyzed quantum-sized SiNWs.

PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE (2021)

Article Materials Science, Multidisciplinary

Silicon Nanowire Solar Cells with μc-Si:H Absorbers for Radial Junction Devices

Letian Dai, Martin Foldyna, Alvarez Jose, Isabelle Maurin, Jean-Paul Kleider, Thierry Gacoin, Pere Roca Cabarrocas

Summary: The researchers successfully developed silicon nanowire radial junction solar cells with higher fill factor and open-circuit voltage by using n-type hydrogenated microcrystalline silicon oxide as a bottom doped layer.

PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE (2021)

Article Physics, Applied

Visualizing the effects of plasma-generated H atoms in situ in a transmission electron microscope☆

Jean-Luc Maurice, Pavel Bulkin, Eric Ngo, Weixi Wang, Martin Foldyna, Ileana Florea, Pere Roca Cabarrocas, Romuald Bejaud, Olivier Hardouin Duparc

Summary: Plasma-generated radicals and atoms can change the surface energies of materials, allowing the preparation of nano-objects that may not stabilize under other conditions, such as Sn-catalyzed silicon nanowires. The presence of plasma can alter the balance of surface energies, stabilizing Sn droplets and enabling efficient growth through the VLS mechanism.

EUROPEAN PHYSICAL JOURNAL-APPLIED PHYSICS (2022)

Article Chemistry, Multidisciplinary

High Density of Quantum-Sized Silicon Nanowires with Different Polytypes Grown with Bimetallic Catalysts

Weixi Wang, Eric Ngo, Ileana Florea, Martin Foldyna, Pere Roca i Cabarrocas, Jean-Luc Maurice

Summary: A novel variant of the vapor-liquid-solid process using bimetallic Cu-Sn catalyst has been developed to grow high-density nanowires with narrow diameter distribution and stable diameter. By controlling the deposited thickness of the catalyst materials, nanowire arrays with an average diameter of 6 nm were achieved, with different polytypes identified through transmission electron microscopy analysis.

ACS OMEGA (2021)

Article Nanoscience & Nanotechnology

Tapering-free monocrystalline Ge nanowires synthesized via plasma-assisted VLS using In and Sn catalysts

Jian Tang, Jun Wang, Jean-Luc Maurice, Wanghua Chen, Martin Foldyna, Linwei Yu, Egor D. Leshchenko, Vladimir G. Dubrovskii, Pere Roca Cabarrocas

Summary: This study demonstrates that plasma-assisted vapor-liquid-solid (PA-VLS) method can be used to synthesize monocrystalline Ge nanowires with In and Sn catalysts, avoiding sidewall deposition issues.

NANOTECHNOLOGY (2022)

Article Energy & Fuels

Triple Radial Junction Hydrogenated Amorphous Silicon Solar Cells with >2 V Open-Circuit Voltage

Chaoqi Wang, Martin Foldyna, Erik Johnson, Pere Roca i Cabarrocas

Summary: The study demonstrates the potential of triple radial junction silicon nanowire solar cells, fabricated using hydrogenated amorphous silicon, for applications requiring high voltages and large surface areas, such as water splitting. High open-circuit voltage and short-circuit current density were achieved by optimizing the SiNW density on substrates, showcasing the efficiency of these solar cells.

SOLAR RRL (2022)

Proceedings Paper Construction & Building Technology

Radial Junction Silicon Nanowire Solar Mini-Modules Grown on FTO/G ass Substrates

Mutaz Al-Ghzaiwat, Martin Foldyna

Summary: A study was conducted on radial junction silicon nanowire solar mini-modules on 5x5 cm FTO/SLG substrates, using plasma-assisted VLS technique. By addressing challenges like high resistive losses, the solar mini-modules achieved a high V-oc of 5.52 V, I-sc of 12.46 mA and FF of 63.56 %, resulting in an eta of 4.37 % and power generation of about 44 mW.

2021 12TH INTERNATIONAL RENEWABLE ENGINEERING CONFERENCE (IREC 2021) (2021)

Article Optics

Colour optimization of phosphor-converted flexible nitride nanowire white light emitting diodes

Nan Guan, Nuno Amador-Mendez, Junkang Wang, Subrata Das, Akanksha Kapoor, Francois H. Julien, Noelle Gogneau, Martin Foldyna, Sudipta Som, Joel Eymery, Christophe Durand, Maria Tchernycheva

JOURNAL OF PHYSICS-PHOTONICS (2019)

Article Energy & Fuels

Highly efficient double-side-passivated perovskite solar cells for reduced degradation and low photovoltage loss

Shahriyar Safat Dipta, Md Habibur Rahaman, Walia Binte Tarique, Ashraful Hossain Howlader, Ayush Pratik, John A. Stride, Ashraf Uddin

Summary: Implementing a double-sided passivation approach can enhance the performance of n-i-p structured PSCs and improve the stability and photovoltaic properties of the cells.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Paste-based silver reduction for iTOPCon rear side metallization

Daniel Ourinson, Andreas Brand, Andreas Lorenz, Marwan Dhamrin, Sebastian Tepner, Michael Linse, Nathalie Goettlicher, Kosuke Tsuji, Jonas D. Huyeng, Florian Clement

Summary: This work presents two approaches to reduce the amount of silver on the rear side of M2-sized industrial iTOPCon solar cells. The Cu-based approach shows promise with similar power conversion efficiency compared to the conventional approach, while the Al-based approach exhibits some limitations but demonstrates the potential of such type of contact for iTOPCon solar cells.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Screen printable copper pastes for silicon solar cells

Abasifreke Ebong, Donald Intal, Sandra Huneycutt, Thad Druffel, Ruvini Dharmadasa, Kevin Elmer, Apolo Nambo

Summary: This study demonstrates the successful metallization of a PERC silicon solar cell using screen-printable copper (Cu) paste. The Cu paste contains antioxidant additives and diffusion inhibitors to prevent oxidation and diffusion of Cu. The Cu-printed cells achieved an efficiency of 19% and showed no Cu diffusion after characterization tests. The long-term stability and effectiveness of the Cu diffusion barrier were also confirmed.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Defining specifications for accurate Metal/TCO specific contact resistivity measurements by TLM in silicon heterojunction devices

Senami Zogbo, Wilfried Favre, Olivier Bonino, Marie-Estelle Gueunier-Farret

Summary: Measuring specific contact resistivity (pc) is crucial for interface engineering in high efficiency solar cells. The Transfer Length Method (TLM) is commonly used for evaluating layer sheet resistance (Rsheet) and pc, but it is not suitable for metal/Transparent Conductive Oxide (TCO) interface evaluation in silicon heterojunction (SHJ) cells. This study investigates the parameters that restrict current confinement within the TCO, including mid-gap trap density (Dit) at the a-Si:H/c-Si interface and the activation energy (Ea = Ec - EF) variation of a-Si:H contact layers.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Ribbons lengthening induced by thermal cycling in PV modules part I: Cell-ribbon mechanical interaction through the solder

Jean-Baptiste Charpentier, Philippe Voarino, Julien Gaume

Summary: The phenomenon of ribbon lengthening in PV modules exposed to thermal cycling is not well explained in the literature. In this study, a three layers model is proposed to explain this effect, and the predictions of the model are validated through finite element method simulations and experiments. The results show that the model predictions are consistent with the indirect measurements, but not with the direct measurements. Additionally, it is inferred that the encapsulant plays a role after the solder failure.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Ribbons lengthening induced by thermal cycling in PV modules, Part II: Glass-ribbon mechanical interaction through the encapsulant

Jean-Baptiste Charpentier, Philippe Voarino, Julien Gaume

Summary: This study investigates the problematic ribbon lengthening observed in PV modules exposed to high amplitude thermal cycling. A simplified system model is proposed and accurate predictions are obtained using the Finite Element Method. The results show that the thickness of the encapsulant has a substantial impact on the lengthening of the ribbons.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Gallium nanoparticles as antireflection structures on III-V solar cells

S. Catalan-Gomez, E. Martinez Castellano, M. Schwarz, M. Montes Bajo, L. Dorado Vargas, A. Gonzalo, A. Redondo-Cubero, A. Gallego Carro, A. Hierro, J. M. Ulloa

Summary: This study investigates the use of core-shell gallium nanoparticles as functional light scatterers on solar cells. By optimizing the nanoparticle size, the short-circuit current of the solar cells is significantly improved. The underlying physical mechanism is studied through optical measurements and simulations, and a method to reduce the plasmonic effect of the nanoparticles is demonstrated.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Highly reflective and passivated ohmic contacts in p-Ge by laser processing of aSiCx:H(i)/Al2O3/aSiC films for thermophotovoltaic applications

M. Gamel, G. Lopez, A. M. Medrano, A. Jimenez, A. Datas, M. Garin, I. Martin

Summary: In this study, a highly reflective ohmic contact to p-type c-Ge material is demonstrated, which can improve the efficiency of thermophotovoltaic devices. The experimental results show that this contact can simultaneously meet the requirements of good back surface passivation, low electrical resistivity, and high reflectivity. Moreover, simulations suggest that implementing these back contacts has the potential to achieve conversion efficiencies comparable to high-efficiency c-Ge TPV cells.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Improvement on solar selective absorption properties of anodic aluminum oxide photonic crystal films by electrodeposition of silver

Hongyang Wei, Qing Xu, Dongchu Chen, Min Chen, Menglei Chang, Xiufang Ye

Summary: This study prepared solar selective absorption films based on anodic aluminum oxide (AAO) photonic crystals using a unique electrodeposition method. The Co-Ag electrodeposited film exhibited superior solar selective absorption properties and thermal stability.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Optical absorption driven by efficient refraction and light concentration for photovoltaic applications

Ankit Kumar, Ankit Chauhan, Jordi Llobet, Helder Fonseca, Patricia C. Sousa, Carlos Calaza, Gil Shalev

Summary: This study found that decorating subwavelength arrays with SiO2 quasi-nanolenses (qNL arrays) can enhance the absorption of the solar spectrum. Optical absorption mechanisms in qNL arrays were investigated using near-field scanning optical microscopy (NSOM), revealing that the enhancement is a result of the combination of effective antireflection coating, increased optical interactions between adjacent dielectrics for elevated light trapping, and strong light concentration due to the presence of qNLs.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Progress on the reduction of silver consumption in metallization of silicon heterojunction solar cells

S. Pingel, T. Wenzel, N. Goettlicher, M. Linse, L. Folcarelli, J. Schube, S. Hoffmann, S. Tepner, Y. C. Lau, J. Huyeng, A. Lorenz, F. Clement

Summary: This study demonstrates the potential to reduce silver consumption in highly efficient SHJ cells through fine-line screen printing using low temperature paste with various screens. The results show that using finer mesh allows for narrower grid fingers and lower resistance, leading to improved cell efficiency. Simulation results indicate that module wire configuration is crucial for reducing silver consumption.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Efficient-thermal conductivity, storage and application of bionic tree-ring composite phase change materials based on freeze casting

Xibo He, Jun Qiu, Wei Wang, Yicheng Hou, Yong Shuai

Summary: This paper proposes a novel phase change material with high thermal conductivity and stability for fast photo-thermal conversion and storage. The experimental results demonstrate excellent durability and stability of the phase change material, with good performance in thermal conductivity and thermal storage efficiency.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Solar evaporation of liquid marbles with tunable nanowire array

Qingyuan Liu, Lin Wang, Zheng Liu, Guohua Liu

Summary: A new evaporating structure consisting of liquid marble with tunable nanowire array is proposed to enhance solar evaporation. The experiments show that the liquid marble with nanowire array exhibits outstanding evaporation performance, which has significant implications for seawater desalination or wastewater treatment.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Effects of different interface on the stability of hybrid heterojunction solar cells

Hao Liu, Qiming Liu, Jinpei Liu, Yonggang Zhao, Yingjie Yu, Yue An, Ganghui Wei, Yanzheng Li, Yujun Fu, Junshuai Li, Deyan He

Summary: Moisture in the air is identified as the main cause of performance degradation in organic-inorganic hybrid solar cells. Exposure to air leads to the growth of thin oxide layer on the interface and the formation of silver sulfide, increasing the series resistance and decreasing the fill factor, thus degrading the cell performance.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Refractive indices and extinction coefficients of p-type doped Germanium wafers for photovoltaic and thermophotovoltaic devices

E. Blanco, P. Martin, M. Dominguez, P. Fernandez-Palacios, I. Lombardero, C. Sanchez-Perez, I. Garcia, C. Algora, M. Gabas

Summary: This study addresses the lack of optical parameters for p-type Ge wafers by determining the complex refractive indices of commercial Ge wafers with varying doping levels. The obtained data successfully reproduces the critical points associated with interband transitions and absorption features below the bandgap. The refractive indices were validated through experimental measurements and solar cell simulations.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)