Corrosion resistance of Hastelloys in molten metal-chloride heat-transfer fluids for concentrating solar power applications

Corrosion rates have been estimated for commercial Hastelloys C-276, C-22 and N types in eutectic molten salts containing NaCl, KCl and ZnCl2 using steady-state potentiodynamic method (0.2 mV s(-1) within similar to +/- 30 mV from the open circuit voltage). Hastelloy C-276 exhibited the lowest corrosion rates of similar to 10 and 40 mu m per year in 13.4NaCl-33.7KCl-52.9ZnCl(2) (mol%) salt at 250 and 500 degrees C, respectively. The potentiodynamic method was validated by conducting traditional immersion test for corrosion rate estimation on C-276 Hastelloy in 13.4NaCl-33.7KCl-52.9ZnCl(2) (mol%) at 500 degrees C (corrosion rate similar to 50 mu m per year). Among the samples evaluated, Hastelloy N showed highest corrosion rate of >150 mu m per year at 500 degrees C. (C) 2014 Elsevier Ltd. All rights reserved.