Article
Food Science & Technology
Fernanda Moreira Oliveira, Raquel Moreira Oliveira, Lucia Tamires Gehrmann Buchweitz, Juliana Rodrigues Pereira, Helen Cristina dos Santos Hackbart, Elen Silveira Nalerio, Caroline Dellinghausen Borges, Rui Carlos Zambiazi
Summary: The study showed that encapsulating olive leaf extract using gelatin and tragacanth gum can enhance encapsulation efficiency and antioxidant activity, contributing to reducing oxidative reactions.
Article
Chemistry, Multidisciplinary
Sonal Choudhary, Kashma Sharma, Manpreet S. Bhatti, Vishal Sharma, Vijay Kumar
Summary: This study synthesized GG-cl-poly(AA) hydrogels based on gellan gum using free radical graft copolymerization. The hydrogels showed excellent water retention capacity and improved moisture properties of plant growth media. The synthesis parameters were optimized using response surface methodology, and the hydrogel degradation behavior was studied. The results suggest that the hydrogel has potential applications in agriculture due to its strong water retention capacity, low cost, and environmental friendliness.
Article
Environmental Sciences
Subhraseema Das, Ganeswar Dalei
Summary: In this study, Schiff-base controlled release fertilizer (CRF) hydrogels composed of dialdehyde xanthan gum (DAXG) and gelatin were fabricated through a simple in situ crosslinking reaction. Increasing the content of DAXG in the hydrogels resulted in a compact network structure. Phytotoxic assay indicated that the hydrogels were non-toxic to different plants. The hydrogels exhibited good water-retention behavior in soil and remained reusable even after 5 cycles. The release of urea from the hydrogels followed a controlled release profile influenced by macromolecular relaxation. Growth assays on Abelmoschus esculentus (Okra) plant provided an intuitive evaluation on the performance of the CRF hydrogel in terms of growth and water-holding capacity. This study demonstrated a facile method for preparing CRF hydrogels to improve urea utilization and soil moisture retention.
SCIENCE OF THE TOTAL ENVIRONMENT
(2023)
Article
Multidisciplinary Sciences
Fatemeh Jamali, Negar Etminani-Esfahani, Abbas Rahmati
Summary: Poly(acrylic acid-co-acrylamide-co-maleic acid) (p(AA-co-AM-co-MA)) superabsorbent polymer was synthesized and its structure, morphology, and strength were characterized. The water absorbency, water retention ability, and reusability of the superabsorbent were investigated, showing high performance in distilled water and saline solution. The response ability of the superabsorbent to temperature, pH, and ionic strength changes was confirmed by swelling and shrinking behavior.
SCIENTIFIC REPORTS
(2023)
Article
Engineering, Environmental
Fatemeh Esmaeildoost, Mohsen Shahrousvand, Alireza Goudarzi, Mohammad B. Bagherieh-Najjar
Summary: Semi-interpenetrating networks (semi-IPNs) of Xanthan gum/poly (acrylic acid) containing Cloisite 15A were prepared and optimized using response surface methodology (RSM). The analysis showed that Cloisite 15A nano-sheets effectively increased the surface area of the hydrogel, which exhibited a porous structure and high adsorption capacity. The XG/PAA/Cloisite 15A hydrogel also demonstrated promising cycling adsorption performance.
JOURNAL OF POLYMERS AND THE ENVIRONMENT
(2022)
Article
Polymer Science
Azin Behravesh, Mohsen Shahrousvand, Alireza Goudarzi
Summary: The synthesis of novel semi-interpenetrating poly(acrylic acid) (PAA)/gum arabic (AG)/ZnO hydrogels was optimized using response surface methodology (RSM), showing that an appropriate amount of gum arabic and cross-linking agent significantly improves the performance of the hydrogels.
IRANIAN POLYMER JOURNAL
(2021)
Article
Engineering, Chemical
Ganeswar Dalei, Subhraseema Das, Soumya Ranjan Jena, Debasis Jena, Jasmine Nayak, Luna Samanta
Summary: This study proposes that in situ crosslinked chitosan-dialdehyde guar gum (CsDAGG) hydrogels can effectively be used for dual drug release in colorectal cancer therapy. Various grades of CsDAGG hydrogels were designed with different amounts of DAGG achieved through periodate oxidation of guar gum. The hydrogels protect the drugs from absorption in the stomach and small intestine, ensuring controlled release at the target site in the colon. The combination of curcumin and aspirin in the hydrogels showed enhanced anticancer effects in colon cancer cells.
CHEMICAL ENGINEERING SCIENCE
(2023)
Article
Polymer Science
Himadri Sekhar Samanta, Samit Kumar Ray
Summary: Interpenetrating network (IPN) hydrogels were successfully prepared by free radical crosslink copolymerization of acrylic acid and guar gum, with varied synthesis variables affecting the properties of the hydrogels. The release kinetics of vitamin B6 from these hydrogels were studied, with the IPN prepared with specific concentrations showing high entrapment efficiency and sustained release rate. The drug release data fitted well to the Korsmeyer-Peppas model.
JOURNAL OF POLYMER RESEARCH
(2021)
Article
Chemistry, Physical
Rok Ambrozic, Igor Plazl
Summary: A novel microfluidic channel device with programmable in situ formation of a hydrogel 3D network was designed, utilizing iron ion-crosslinked alginate as the active porous medium. The controlled sol-gel transition and release of target molecules demonstrate the programmable nature and wide-ranging application potential of the electrically responsive material. Optimized diffusion of entrapped molecules was achieved by varying dissolution conditions and initial formulations.
Article
Pharmacology & Pharmacy
Atul Garkal, Amelia Avachat
Summary: This study developed a novel pH-responsive in-situ gelling sustained-release nevirapine pediatric suspension (SRNPS) for the treatment and prevention of mother-to-child transmission of HIV. The SRNPS demonstrated good in-situ gelling behavior and sustained drug release, leading to improved patient compliance.
JOURNAL OF DRUG DELIVERY SCIENCE AND TECHNOLOGY
(2022)
Article
Biochemistry & Molecular Biology
Pragnesh N. Dave, Pradip M. Macwan, Bhagvan Kamaliya
Summary: The study aimed to understand the drug release characteristics of Gg-cl-poly(NIPA-co-AA)/CoFe2O4 hydrogel containing metformin hydrochloride. Gum ghatti-based hydrogel with acrylic acid and N-isopropylacrylamide as graft copolymers was used for controlled release. The hydrogel was characterized using FTIR, SEM, TGA, and DSC. Drug release occurred through diffusion and polymer relaxation, regardless of drug solubility. In vitro release studies at different pH values showed pH 7.4 as the optimal pH for maximum release. The hydrogel loaded with metformin hydrochloride exhibited sustained release, fitting the Korsmeyer-Peppas model with a specific case II transport mechanism.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Chemistry, Multidisciplinary
Saahil Sheth, Samuel Stealey, Nicole Y. Morgan, Silviya P. Zustiak
Summary: Hydrogel microspheres are widely used in biomedical applications, but the challenge lies in mixing precursor solutions for timed gelation systems. Through the design and evaluation of mixing devices, the serpentine geometry with a pillar array was found to be the most effective in fully mixing precursor solutions and enabling the fabrication of monodisperse microspheres.
Article
Polymer Science
Vasudha Vaid, Rajeev Jindal
Summary: This study developed an eco-friendly, cost-effective, and efficient adsorbent using a cross-linked 3-D network hydrogel based on kappa-carrageenan (KCG) and tamarind kernel powder (TKP). The hydrogel exhibited a high adsorption capacity for the removal of brilliant green (BG) and rose bengal (RB) dyes from wastewater. The adsorption capacity was influenced by parameters such as dye concentration, pH, temperature, and adsorbent amount. The kinetic, isotherm, and thermodynamic studies showed that the hydrogel followed pseudo-second-order kinetics and the Langmuir isotherm model.
JOURNAL OF APPLIED POLYMER SCIENCE
(2022)
Article
Pharmacology & Pharmacy
Vasudha Vaid, Rajeev Jindal
Summary: The present research focuses on the synthesis and optimization of a natural polysaccharide-based hydrogel using air and epichlorohydrin as a crosslinker. The study investigates the influence of various process variables on the hydrogel's properties and characterizes the resulting hydrogel and inclusion complexes. The research also explores the controlled release of adenosine under different conditions.
JOURNAL OF DRUG DELIVERY SCIENCE AND TECHNOLOGY
(2022)
Article
Chemistry, Multidisciplinary
Sonal Choudhary, Kashma Sharma, Manpreet S. Bhatti, Vishal Sharma, Vijay Kumar
Summary: This study synthesized GG-cl-poly(AA) hydrogels based on gellan gum using free radical graft copolymerization. The hydrogels showed excellent water retention capacity and improved moisture properties of plant growth media. The synthesis parameters were optimized using response surface methodology, and the hydrogel degradation behavior was studied. The results suggest that the hydrogel has potential applications in agriculture due to its strong water retention capacity, low cost, and environmental friendliness.
Article
Biochemistry & Molecular Biology
Khushbu, Rajeev Jindal
Summary: The objective of the study is to enhance the solubility and stability of edaravone, a free radical scavenger drug. The inclusion complexes and nanocomposites were prepared and characterized, and their drug release behaviors were investigated. The results demonstrated that the nanocomposites showed better performance in controlled drug release.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2022)
Article
Polymer Science
Khushbu, Rajeev Jindal
Summary: Natural polysaccharides were used as adsorbents for the removal of toxic dyes. Nanocomposites of chitosan, graphene oxide, sodium alginate, and beta-cyclodextrin were synthesized and their adsorption performance was studied. GO/ALG/CH/beta-CD nanocomposite showed higher adsorption capacity and the adsorption process followed the pseudo-second-order kinetics.
IRANIAN POLYMER JOURNAL
(2022)
Article
Polymer Science
Khushbu, Rajeev Jindal
Summary: This study aimed to prepare an inclusion complex of adenosine (ADS) and beta-cyclodextrin (beta-CD) that can be incorporated into a nanocomposite system for topical administration. Different methods were used to fabricate the inclusion complex, and the effects of bentonite on adenosine release were investigated. Optimization of reaction parameters was carried out using response surface methodology (RSM), and the influence of beta-CD on polymer relaxation and drug release was analyzed.
JOURNAL OF APPLIED POLYMER SCIENCE
(2022)
Article
Polymer Science
Khushbu, Rajeev Jindal
Summary: This study aims to optimize the performance of graphene oxide incorporated chitosan and sodium alginate-based nanocomposite and investigate the drug loading and release behavior of Paracetamol. The results showed that graphene oxide has excellent biocompatibility and high drug loading capacity, and the inclusion interaction with β-CD can slow down the drug release rate.
Article
Engineering, Chemical
Ambika Sharma, Manpreet Singh Bhatti
Summary: This study examined the efficacy of using a sequencing batch reactor (SBR) to treat high-strength organic wastewater for the removal of both COD and nutrients. The results showed that with the appropriate cycle time and C:N:P ratio, significant removal of COD, NH3-N, and PO43--P could be achieved. Statistical analysis also revealed the impact of different process variables on wastewater treatment, as well as the settleability of sludge.
Article
Multidisciplinary Sciences
Sunita Kesar, Manpreet S. Bhatti
Summary: This study provides detailed information on the usefulness of chlorination in treating sewage for irrigation purposes. Chlorination is a cost-effective method for disinfection. The study optimized the disinfection process using sodium hypochlorite and investigated various process variables. The results showed that certain kinetic models fit well with the experimental data of chlorine disinfection.
Article
Environmental Sciences
Anjali Singh, Balbir Singh Kaith, Dhiraj Sud, Manpreet Singh Bhatti
Summary: A novel eco-friendly semi-interpenetrating network (semi-IPN) device was prepared from functionally modified natural backbone (Colocasia esculenta) for controlled release of fertilizers. The device showed excellent potential as a controlled agrochemical release system, with fertilizer release mechanism following the Korsmeyer-Peppas Model (Fickian diffusion) in water media at different pH values. Furthermore, the device demonstrated significant degradation in vermi-compost method, making it an effective approach for sustained agriculture.
WATER AIR AND SOIL POLLUTION
(2023)
Article
Polymer Science
Anjali Singh, Balbir Singh Kaith, Rohit Mehra, C. S. Sreejay, Balram Lohan, Manpreet Singh Bhatti
Summary: In this study, a semi-interpenetrating network was prepared to effectively utilize the natural polysaccharides of okra mucilage and psyllium husk fibre. The cross-linked networks showed a maximum swelling percentage of 355% and were further explored for the removal of uranyl(VI) ions from aqueous media. The synthesized adsorbent exhibited excellent uptake efficiency, indicating its promising potential in commercial industrial waste treatment.
POLYMER SCIENCE SERIES B
(2023)
Article
Chemistry, Physical
Anjali Singh, Balbir Singh Kaith, Rohit Mehra, Vikas Balram, Vikas Sardul, Manpreet Singh Bhatti
Summary: The goal of this study was to synthesize an eco-friendly okra-psyllium based hydrogel using citric acid-ammonium persulfate as a crosslinker-initiator system. Various techniques were used to analyze the morphology, structure, and thermal behavior of the synthesized hydrogel. The hydrogel showed high grafting percentage and swelling percentage. It also exhibited excellent adsorption behavior for the removal of uranium and crystal violet dye from contaminated water.
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS
(2023)
Article
Multidisciplinary Sciences
Tanbir Singh, Yutaka Matsumi, Tomoki Nakayama, Sachiko Hayashida, Prabir K. Patra, Natsuko Yasutomi, Mizuo Kajino, Kazuyo Yamaji, Pradeep Khatri, Masayuki Takigawa, Hikaru Araki, Yuki Kurogi, Makoto Kuji, Kanako Muramatsu, Ryoichi Imasu, Anamika Ananda, Ardhi A. Arbain, Khaiwal Ravindra, Sanjeev Bhardwaj, Sahil Kumar, Sahil Mor, Surendra K. Dhaka, A. P. Dimri, Aka Sharma, Narendra Singh, Manpreet S. Bhatti, Rekha Yadav, Kamal Vatta, Suman Mor
Summary: An intensive field campaign was conducted in 2022 in northern India, specifically in the states of Punjab, Haryana, and Delhi NCR, to study the exposure to PM2.5. The campaign utilized 29 Compact and Useful PM2.5 Instrument with Gas sensors (CUPI-Gs) for continuous observations. The study found that the PM2.5 levels in the region gradually increased from less than 60μg/m³ in October to up to 500μg/m³ in November, with two distinct plumes of PM2.5 exceeding 500μg/m³ traced back to crop residue burning in Punjab.
SCIENTIFIC REPORTS
(2023)
Article
Engineering, Chemical
Aditi Sugha, Manpreet S. Bhatti
Summary: In this study, the degradation of methylene blue dye using UV/H2O2 advanced oxidation process was investigated. The results showed that an acidic pH and higher H2O2 concentration can effectively enhance the decolorization efficiency. In particular, a dosage of 12.5 mM H2O2 achieved the optimal removal effect.
DESALINATION AND WATER TREATMENT
(2022)
Article
Chemistry, Multidisciplinary
Rekha Yadav, Aditi Sugha, Manpreet S. Bhatti, Sushil K. Kansal, Sudhir K. Sharma, Tuhin K. Mandal
Summary: This study analyzed fog samples collected from the rooftop of Guru Nanak Dev University in Amritsar, India, and found that sulfate was the dominant pollutant in the fog, mainly originating from vehicular exhaust emissions from burning fossil fuels. Multiple regression analysis showed that the PM2.5/PM10 ratio and relative humidity have an exponential effect on visibility.
Article
Chemistry, Physical
Yiping Yin, Zhe Wang, Hua Zou
Summary: This study presents a novel method for preparing dimpled polymer-silica nanocomposite particles using interfacial swelling-based seeded polymerization. The optimized conditions allow for a relatively high percentage of dimpled particles to be achieved.
Article
Chemistry, Physical
Brenden D. Hoehn, Elizabeth A. Kellstedt, Marc A. Hillmyer
Summary: Porous materials with nanometer-scale pores have important applications as nanoporous membranes. In this study, ABA triblock copolymers were used as precursors to produce nanoporous polymeric membranes (NPMs) in thin film form by degrading the end blocks. Polycyclooctene (PCOE) NPMs with tunable pore sizes were successfully prepared using solvent casting technique. Oxygen plasma etching was employed to improve the surface porosity and hydrophilicity of the membranes. This study provides a straightforward method to produce tough NPMs with high porosity and hydrophilic surface properties.
Article
Chemistry, Physical
Vladislav S. Petrovskii, Stepan I. Zholudev, Igor I. Potemkin
Summary: This article investigates the behavior of linear and ring polypeptide chains in aqueous solution and explores the properties of the complexes formed by these chains with oppositely charged surfactants. The results demonstrate that the complexes of linear supercharged unfolded polypeptides and the corresponding surfactants exhibit impressive adhesive properties.
Article
Chemistry, Physical
Merve Cevik, Serkan Dikici
Summary: Cardiovascular diseases are a leading cause of death globally, and vascular grafts are a promising treatment option. This study focuses on tissue-engineered vascular grafts (TEVGs) using decellularized parsley stems as a potential biomaterial. The decellularized parsley stems showed suitable properties for TEVGs, providing a suitable environment for human endothelial cells to form a pseudo endothelium. This study showcases the potential of using parsley stems for TEVGs.
Article
Chemistry, Physical
Gustavo A. Vasquez-Montoya, Tadej Emersic, Noe Atzin, Antonio Tavera-Vazquez, Ali Mozaffari, Rui Zhang, Orlando Guzman, Alexey Snezhko, Paul F. Nealey, Juan J. de Pablo
Summary: The optical properties of liquid crystals are typically controlled by electric fields. In this study, we investigate the effects of microfluidic flows and acoustic fields on the molecular orientation and optical response of nematic liquid crystals. We identify several previously unknown structures and explain them through calculations and simulations. These findings hold promise for the development of new systems combining sound, flow, and confinement.
Article
Chemistry, Physical
Xinjun Wu, Xin Guan, Shushu Chen, Jiangpeng Jia, Chongyi Chen, Jiawei Zhang, Chuanzhuang Zhao
Summary: This research presents a novel shape memory hydrogel with a remodelable permanent shape and programmable cold-induced shape recovery behavior. The hydrogel is prepared using specific treatment methods to achieve shape fixation by heating and shape recovery by cooling. Additionally, deformable devices can be obtained by assembling hydrogel blocks with different concentrations.
Article
Chemistry, Physical
Rebecca Hengsbach, Gerhard Fink, Ulrich Simon
Summary: This study examines the properties of DNA functionalized pNipmam microgels and pure pNipmam microgels at different concentrations of sodium chloride and in PBS solutions using temperature dependent H-1-NMR measurements. The results show that DNA modification affects the volume phase transition temperature and the addition of salt and PBS further enhances this effect.
Article
Chemistry, Physical
Ningyi Li, Junhong Li, Lijingting Qing, Shicheng Ma, Yao Li, Baohui Li
Summary: This paper investigates the self-assembly behavior of colloids with competing interactions under spherical confinement and finds that different ordered structures can be formed under different sized spherical confinements. Moreover, more perforated structures are formed in smaller spheres.