4.4 Article

Synthesis and Properties of High Oil-Absorbing Resins with Long Chain by High Internal Phase Emulsions as Template

Journal

SEPARATION SCIENCE AND TECHNOLOGY
Volume 49, Issue 16, Pages 2518-2524

Publisher

TAYLOR & FRANCIS INC
DOI: 10.1080/01496395.2014.928322

Keywords

high oil-absorbing resin; high internal phase emulsions; template

Funding

  1. National Natural Scientific Foundation of China [20904018, 51073075]
  2. Program for New Century Excellent Talents in University [NCET-11-1028]
  3. Natural Science Foundation for Distinguished Young Scholars of Shandong province [JQ201203]
  4. Shandong Provincial Natural Science Foundation of China [ZR2010BQ007]

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Synthesis of porous high oil-absorbing resins by high internal phase emulsions (HIPEs) as template was described. Lauryl methacrylate (LMA), hexadecyl methacrylate (HMA), and steary methacrylate (SMA) with long-chain alkyl groups were chosen as monomers to prepare high oil-absorbing resins. Effects of different factors including initiator, crosslinker, emulsifying agent, porogen, reaction temperature, reaction time, and volume ratio of water/oil on oil-absorbing capacity were discussed. The maximum capacities of the high oil-absorbing resins prepared by LMA, HMA, and SMA were 24 g.g(-1), 32 g.g(-1), and 34 g.g(-1) in trichloromethane, respectively. The oil-absorbing capacities of these resins remain constant after three times desorption and absorption processes.

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