4.4 Article

Application of Water-Miscible Alcohol-Based Aqueous Two-Phase Systems for Extraction of Dyes

Journal

SEPARATION SCIENCE AND TECHNOLOGY
Volume 46, Issue 8, Pages 1283-1288

Publisher

TAYLOR & FRANCIS INC
DOI: 10.1080/01496395.2010.551168

Keywords

alcohol; aqueous two-phase extraction; citrate; methyl orange; phosphate; rhodamine B

Funding

  1. National Natural Science Foundation of China [21076098, 20976074]
  2. National Science Foundation of Jiangsu Province [BK2010349]

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The water-miscible alcohols (ethanol, 1-propanpol, 2-propanol) were used to form aqueous two-phase systems with K2HPO4 and Na2HPO4. Meanwhile, the organic citrates were also investigated as the phase-separation salts. The effects of the types and concentrations of phase-forming substances as well as temperature on the formation of aqueous two-phase systems were discussed. The alcohol (ethanol, 1-propanpol, 2-propanol)-salt (K2HPO4, K3C6H5O7, (NH4)3C6H5O7) aqueous two-phase systems were used to extract Rhodamine B and methyl orange in aqueous solution. It proved that the water-miscible alcohol-salt (inorganic salt, organic salt) aqueous two-phase systems can be both used to extract hydrophilic targets directly without adding any reaction reagents. The aqueous two-phase extraction process was also discussed.

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