4.7 Article

Evaluation of n-type ternary metal oxide NiMn2O4 nanomaterial for humidity sensing

Journal

SENSORS AND ACTUATORS B-CHEMICAL
Volume 191, Issue -, Pages 837-843

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2013.10.071

Keywords

NiMn2O4; Oleic acid; Nanoparticles; Impedance; Humidity; Sensor

Funding

  1. CSIR

Ask authors/readers for more resources

Synthesis of mono-dispersed oleic acid (OA) capped NiMn2O4 (NMO) nanoparticles and their use for humidity sensing is reported. Oleic acid capped NMO (NMO-cOA) nanoparticles are synthesized from nickel oleate and manganese oleate complex. NiMn2O4 is obtained by removing oleic acid capping at 500 degrees C in air. X-ray diffraction analysis shows formation of pure NiMn2O4 phase which is also confirmed by HRTEM-SAED analysis. The TEM analysis also shows that the nanoparticles are nearly mono-dispersed. Doctor bladed films of NMO nanoparticles are seen to exhibit excellent humidity sensing property. The resistivity is seen to change by two orders with humidity change from 11% RH to 92% RH with fairly good linearity over the entire range. The response and recovery times are also fast. (C) 2013 Elsevier B.V. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Chemistry, Multidisciplinary

The Effect of Alkyl Spacers on the Mixed Ionic-Electronic Conduction Properties of N-Type Polymers

Iuliana P. Maria, Bryan D. Paulsen, Achilleas Savva, David Ohayon, Ruiheng Wu, Rawad Hallani, Aniruddha Basu, Weiyuan Du, Thomas D. Anthopoulos, Sahika Inal, Jonathan Rivnay, Iain McCulloch, Alexander Giovannitti

Summary: The study introduces two copolymers with alkyl-glycol side chains for improved performance of n-type materials in aqueous electrolytes. It is found that these polymers with alkyl spacers exhibit excellent performance in OECTs with remarkable stability.

ADVANCED FUNCTIONAL MATERIALS (2021)

Article Chemistry, Physical

Laser patterning of boron carbon nitride electrodes for flexible micro-supercapacitor with remarkable electrochemical stability/capacity

Indrapal Karbhal, Aniruddha Basu, Apurva Patrike, Manjusha V. Shelke

Summary: A high performance all solid-state planar micro-supercapacitor with interdigitated BCN electrodes was fabricated using a fast, scalable laser patterning technique. The device showed high specific capacitance and electrochemical stability, even after repeated bending and cycling tests, demonstrating remarkable flexibility.

CARBON (2021)

Article Chemistry, Physical

Adduct-based p-doping of organic semiconductors

Nobuya Sakai, Ross Warren, Fengyu Zhang, Simantini Nayak, Junliang Liu, Sameer V. Kesava, Yen-Hung Lin, Himansu S. Biswal, Xin Lin, Chris Grovenor, Tadas Malinauskas, Aniruddha Basu, Thomas D. Anthopoulos, Vytautas Getautis, Antoine Kahn, Moritz Riede, Pabitra K. Nayak, Henry J. Snaith

Summary: Adducts of dimethyl sulfoxide and hydrobromic acid can efficiently p-dope various organic semiconductors and are compatible with other counterions, showing promise for improving stability and performance parameters of organic optoelectronic devices.

NATURE MATERIALS (2021)

Review Chemistry, Multidisciplinary

Doping Approaches for Organic Semiconductors

Alberto D. Scaccabarozzi, Aniruddha Basu, Filip Anies, Jian Liu, Osnat Zapata-Arteaga, Ross Warren, Yuliar Firdaus, Mohamad Insan Nugraha, Yuanbao Lin, Mariano Campoy-Quiles, Norbert Koch, Christian Mueller, Leonidas Tsetseris, Martin Heeney, Thomas D. Anthopoulos

Summary: This article reviews the important advances in organic semiconductor doping and its applications. It discusses the relevant physical processes, established mechanisms, and newly proposed theories. It also provides a comprehensive summary of the most widely studied dopants to date, with a particular focus on the chemical strategies for synthesizing molecules with improved functionality. The article further explores the processing routes for doped organic films and the important relationships between doping, processing, and nanostructure. Lastly, it highlights how doping can enhance the operating characteristics of various organic devices.

CHEMICAL REVIEWS (2022)

Article Chemistry, Multidisciplinary

Silver nanoparticles decorated on graphene oxide modified polyester fabric: Catalytic reduction of 4-nitrophenol, organic dyes and SERS application

Keshav Sharma, Mohd Ali, Renuka Singh, Shukla Majhi, Surbhi Sharma, Chandra Shekhar Pati Tripathi, Debanjan Guin

Summary: This study reports on the immobilization of silver nanoparticles on functional graphene oxide modified polyester fabric for catalytic reduction of organic pollutants. The catalyst showed outstanding performance in reducing 4-nitrophenol, methyl orange and methyl red, and the reduction process was monitored using surface enhanced Raman scattering. The developed catalyst exhibited excellent stability and reusability for both catalytic reduction and SERS sensing.

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS (2022)

Article Polymer Science

N-type polymer semiconductors incorporating para, meta, and ortho-carborane in the conjugated backbone

Filip Anies, Zhuoran Qiao, Mohamad Insan Nugraha, Aniruddha Basu, Thomas D. Anthopoulos, Nicola Gasparini, Martin Heeney

Summary: This study reports three novel n-type conjugated polymer semiconductors incorporating carborane in the polymer backbone and demonstrates their applicability in optoelectronic devices. The optoelectronic properties of para-, meta-, and ortho-carborane isomers were compared and similar energetic characteristics were found between the different polymers. The carborane unit in the polymer acts as a conjugation breaker, confining electron delocalisation to the conjugated moieties. Fabrication of all-polymer organic photovoltaic (OPV) devices and thin-film transistors (TFTs) showed differences in device performance, with the meta-carborane based polymer exhibiting superior performance in both OPV and TFT devices.

POLYMER (2022)

Article Chemistry, Multidisciplinary

Y6 Organic Thin-Film Transistors with Electron Mobilities of 2.4 cm2 V-1 s-1 via Microstructural Tuning

Edgar Gutierrez-Fernandez, Alberto D. Scaccabarozzi, Aniruddha Basu, Eduardo Solano, Thomas D. Anthopoulos, Jaime Martin

Summary: The study demonstrates that using the commonly used nonfullerene acceptor BTP-4F can achieve organic thin-film transistors with high electron mobility, opening up new possibilities in the field of organic electronics. Efficient charge transport is linked to highly ordered crystalline structure, providing a new approach for exploring high mu(e) organic materials.

ADVANCED SCIENCE (2022)

Article Energy & Fuels

Generation of long-lived charges in organic semiconductor heterojunction nanoparticles for efficient photocatalytic hydrogen evolution

Jan Kosco, Soranyel Gonzalez-Carrero, Calvyn T. Howells, Teng Fei, Yifan Dong, Rachid Sougrat, George T. Harrison, Yuliar Firdaus, Rajendar Sheelamanthula, Balaji Purushothaman, Floriana Moruzzi, Weidong Xu, Lingyun Zhao, Aniruddha Basu, Stefaan De Wolf, Thomas D. Anthopoulos, James R. Durrant, Iain McCulloch

Summary: Organic semiconductor heterojunction photocatalysts have the potential to efficiently drive hydrogen evolution for solar fuel synthesis. By optimizing the structure of heterojunction photocatalysts, the generation of long-lived reactive charges can be greatly enhanced, enabling potential applications in water-splitting and slow oxidation reactions.

NATURE ENERGY (2022)

Article Chemistry, Multidisciplinary

Ultra-Narrowband Near-Infrared Responsive J-Aggregates of Fused Quinoidal Tetracyanoindacenodithiophene

Qiao He, Aniruddha Basu, Hyojung Cha, Matyas Daboczi, Julianna Panidi, Luxi Tan, Xiantao Hu, Chi Cheng Huang, Bowen Ding, Andrew J. P. White, Ji-Seon Kim, James R. Durrant, Thomas D. Anthopoulos, Martin Heeney

Summary: A new class of J-aggregating materials based on quinoidal indacenodithiophenes (IDTs) with ultra-narrowband NIR absorption peak is reported. The spectral width can be tuned by the length of the solubilizing alkyl group. The J-aggregate behavior is confirmed and their utility as electron-transporting materials is demonstrated.

ADVANCED MATERIALS (2023)

Article Electrochemistry

Electrochemical Sensing Platform based on Greenly Synthesized Gum Arabic Stabilized Silver Nanoparticles for Hydrogen Peroxide and Glucose

Keshav Sharma, Shukla Majhi, Chandra Shekhar Pati Tripathi, Debanjan Guin

Summary: Gum Arabic stabilized silver nanoparticles (GA-Ag NPs) were synthesized using a green synthesis method and exhibited excellent electrocatalytic behavior for H2O2 and glucose sensing.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2022)

Article Polymer Science

N-type polymer semiconductors incorporating heteroannulated benzothiadiazole

Xiantao Hu, Aniruddha Basu, Martina Rimmele, Adam V. V. Marsh, Filip Anies, Qiao He, Thomas D. D. Anthopoulos, Martin Heeney

Summary: We report the synthesis and characterization of four novel n-type polymer semiconductors containing a 2-(1,3-dithiol-2-ylidene)malonitrile (DTYM) group as an acceptor and a 2,1,3-benzothiadiazole (BT) unit. The introduction of the DTYM group leads to backbone twisting and blue-shifted absorption, but increases the dipole moment and electron affinity. All polymers exhibit n-type semiconducting character in organic field-effect transistors (OFETs), with the fluorinated bithiophene donor demonstrating the best performance. This work highlights the influence of the DTYM group on polymer semiconductors and its potential as a functional group to enhance electron affinity.

POLYMER CHEMISTRY (2023)

Article Chemistry, Analytical

Gum Arabic-mediated synthesis of silver nanoparticles for their applications as colorimetric and SERS-based detection of hydrogen peroxide

Shukla Majhi, Ashish Kumar, Surbhi Sharma, Chandra Shekhar Pati Tripathi, Debanjan Guin

Summary: This study reports on a one-step green method for synthesizing Gum Arabic stabilized silver nanoparticles (GA-Ag NPs) and demonstrates their potential applications in detecting H2O2 and glucose, showing good detection performance and feasibility.

ANALYTICAL SCIENCES (2023)

Article Chemistry, Multidisciplinary

Palladium nanoparticles on polydimethylsiloxane film for C-C coupling reactions, and catalytic reduction of organic pollutants in water

Shukla Majhi, Renuka Singh, Keshav Sharma, Chandra Shekhar Pati Tripathi, Debanjan Guin

Summary: In this study, a novel method for immobilizing Palladium nanoparticles onto a polydimethylsiloxane support was presented. The stability of Palladium nanoparticles on the polydimethylsiloxane surface was enhanced by functionalizing it with amine groups. The resulting material was characterized, and its catalytic performance in the reduction of environmental pollutants and carbon-carbon coupling reactions was investigated.

CHEMISTRYSELECT (2023)

Article Materials Science, Multidisciplinary

Doping-induced decomposition of organic semiconductors: a caveat to the use of Lewis acid p-dopants

Georgios Rotas, Giannis Antoniou, Paris Papagiorgis, Aniruddha Basu, Julianna Panidi, Petr Ufimkin, Leonidas Tsetseris, Grigorios Itskos, Martin Heeney, Georgios C. Vougioukalakis, Thomas D. Anthopoulos, Panagiotis E. Keivanidis

Summary: Solution-processable molecular dopants are commonly used to tune the electronic properties of organic semiconductors. However, the exact doping mechanism and the products of doping reactions are not fully understood. This study focuses on the chemical integrity of PTAA and diF-TES-ADT organic semiconductors after p-doping with the Lewis acid agent B(C6F5)3, revealing potential decomposition reactions and implications for device stability.

JOURNAL OF MATERIALS CHEMISTRY C (2022)

Article Materials Science, Multidisciplinary

The influence of alkyl group regiochemistry and backbone fluorination on the packing and transistor performance of N-cyanoimine functionalised indacenodithiophenes

Thomas Hodsden, Karl J. Thorley, Aniruddha Basu, Andrew J. P. White, Changsheng Wang, William Mitchell, Florian Glocklhofer, Thomas D. Anthopoulos, Martin Heeney

Summary: The synthesis of two novel n-type molecular organic semiconductors based on a fluorinated indacenodithiophene core in combination with an electron withdrawing N-cyanoimine group is reported. The N-cyanoimine is confirmed to be a strongly electron accepting group, which in combination with the core fluorination resulted in high electron affinities for both materials. Significant differences in electron transfer integrals for the two regioisomers were observed, relating to differences in relative molecular displacement along the pi-stacking direction.

MATERIALS ADVANCES (2021)

Article Chemistry, Analytical

MEMS sensor based on MOF-derived WO3-C/In2O3 heterostructures for hydrogen detection

Mengmeng Guo, Na Luo, Yueling Bai, Zhenggang Xue, Qingmin Hu, Jiaqiang Xu

Summary: A porous heterostructure WO3-C/In2O3 was designed and prepared for a miniature H2 sensor, which showed higher response value, lower operating temperature, fast response-recovery speed, and low limit of detection.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Signal amplification strategy by chitosan-catechol hydrogel modified paper electrode for electrochemical detection of trace arsenite

Feng Hu, Hui Hu, Yuting Li, Xiaohui Wang, Xiaowen Shi

Summary: Arsenic contamination in water bodies is a significant health risk. This study developed a chitosan-catechol modified electrode for rapid and accurate detection of trace amounts of arsenic. The modified electrode demonstrated good detection capability and resistance to ionic interference, making it suitable for in situ detection.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

A buffering fluorogenic probe for real-time lysosomal pH monitoring

Yantao Zhang, Qian Liu, Tao Tian, Chunhua Xu, Pengli Yang, Lianju Ma, Yi Hou, Hui Zhou, Yongjun Gan

Summary: In this study, a lysosome-targeting buffering fluorogenic probe (Lyso-BFP) was designed and synthesized, demonstrating excellent photostability, pH specificity, and responsiveness to lysosomal acidification in living cells. The performance of Lyso-BFP in pH sensing was attributed to the inhibition of the photo-induced electron transfer process. Lyso-BFP allowed for wash-free imaging and long-term real-time monitoring of lysosome pH changes based on its off-on fluorescence behavior and buffer strategy.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Rational design of α-glucosidase activated near-infrared fluorescent probe and its applications in diagnosis and treatment of diabetes

Wei Cai, Wenbo Sun, Jiayue Wang, Xiaokui Huo, Xudong Cao, Xiangge Tian, Xiaochi Ma, Lei Feng

Summary: In this study, a near-infrared fluorescent probe HCBG was developed for imaging of alpha-GLC. HCBG exhibited excellent selectivity and sensitivity towards alpha-GLC in complex bio-samples, and showed good cell permeability for in situ real-time imaging. Through the high-throughput screening system established by HCBG, a natural alpha-GLC inhibitor was successfully isolated and identified. This study provides a novel fluorescence visualization tool for discovering and exploring the biological functions of diabetes-related gut microbiota, and a high-throughput screening approach for alpha-GLC inhibitor.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Electrochemical immunosensor for the quantification of galectin-3 in saliva

Trey W. Pittman, Xi Zhang, Chamindie Punyadeera, Charles S. Henry

Summary: Heart failure is a growing epidemic and a significant clinical and public health problem. Researchers have developed a portable and affordable diagnostic device for heart failure that can be used at the point-of-care, providing a valid alternative to current diagnostics approaches.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Optical hydrogen peroxide sensor for measurements in flow

Anders O. Tjell, Barbara Jud, Roland Schaller-Ammann, Torsten Mayr

Summary: An optical hydrogen peroxide sensor based on catalytic degradation and the detection of produced oxygen is presented. The sensor offers higher resolution and better sensitivity at lower H2O2 concentrations. By removing O2 from the sample solution, a more sensitive O2 sensor can be used for measurement. The sensor has been successfully applied in a flow-through cell to measure H2O2 concentration in different flow rates.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Engineered vertically-aligned carbon nanotube microarray for self-concentrated SERS detection

Seong Jae Kim, Ji-hun Jeong, Gaabhin Ryu, Yoon Sick Eom, Sanha Kim

Summary: Surface-enhanced Raman spectroscopy (SERS) is a high-sensitivity, label-free detection method with various analytical applications. Researchers have developed a hydrophobic SERS substrate based on engineered carbon nanotube arrays (CNT-SERS) and studied the role of structural design at both micro and nanoscales. The substrate demonstrated controlled self-enrichment capability and enhanced sensitivity, with a significant increase in the SERS signal. The study also proposed a theoretical model and a concentration strategy inspired by plants for analyte deposition on microarrays.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Flexible enzyme-like platform based on a 1-D CeVO4/2-D rGO-MCC heterostructure as sensor for the detection of intracellular superoxide anions

Dan Zhao, Renjun Jiang, Xiaoqiang Liu, Subbiah Alwarappan

Summary: In this study, a novel ternary composite material was constructed by assembling cerium vanadate nanorods on reduced graphene oxide-microcrystalline cellulose nanosheets, and it was used for real-time monitoring of the concentration of superoxide anions in vivo. The ternary composite showed excellent conductivity, large surface area, and abundant active sites, leading to a wider linear range, high sensitivity, low detection limit, and fast response time for superoxide anion detection.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Covalent organic framework enhanced aggregation-induced emission of berberine and the application for detection

Tengfei Wang, Liwen Wang, Guang Wu, Dating Tian

Summary: In this study, a covalent organic framework material TaTp-COF with porous and uniform spheres was successfully prepared via hydrothermal reaction, and it was found to significantly enhance the aggregation-induced emission (AIE) of berberine. The unique emission properties of berberine on TaTp-COF were studied and utilized for the sensitive detection of berberine.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Visualized time-temperature monitoring by triplet-sensitized ratiometric fluorescent nanosensors

Lin Li, Yilei Ding, Lei Xu, Shuoran Chen, Guoliang Dai, Pengju Han, Lixin Lu, Changqing Ye, Yanlin Song

Summary: In this study, a novel TTI based on a ratiometric fluorescent nanosensor is designed, which has the advantages of high accuracy and low cost. Experimental and theoretical investigations confirm its pH responsiveness and demonstrate its good sensitivity and reliability. By monitoring the total volatile basic nitrogen, this TTI can accurately predict food spoilage and can be adaptively modified for different types of food. The TTI based on this nanosensor enables visual monitoring of food quality.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

A fluorescent prodrug to fight drug-resistant lung cancer cells via autophagy-driven ferroptosis

Fangju Chen, Xueting Wang, Wei Chen, Chenwen Shao, Yong Qian

Summary: Lung cancer is the second most common malignant tumor worldwide. Drug resistance in lung cancer leads to treatment failure and recurrence in majority of patients. This study developed a fluorescent prodrug that can be activated in cancer cells to release drugs, and its signal can be tracked by imaging. It shows a unique autophagy-driven ferroptosis effect, indicating its potential for targeting drug-resistant cancer cells.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

ZnO quantum dots sensitized ZnSnO3 for highly formaldehyde sensing at a low temperature

Weichao Li, Qiming Yuan, Zhangcheng Xia, Xiaoxue Ma, Lifang He, Ling Jin, Xiangfeng Chu, Kui Zhang

Summary: This study developed a high-performance gas sensor for formaldehyde detection by modifying ZnSnO3 with ZnO QDs and SnO2 QDs. The modified sensor showed improved sensing response and lower working temperature. The presence of ZnO QDs formed rich heterojunctions, increased surface area, and provided oxygen deficiency for formaldehyde sensing reaction, thus enhancing the sensor performance. This research provides an alternative method to enhance the sensing properties of MOS by QDs modification.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Development of highly sensitive plasmonic biosensors encoded with gold nanoparticles on M13 bacteriophage networks

Joung-Il Moon, Eun Jung Choi, Younju Joung, Jin-Woo Oh, Sang-Woo Joo, Jaebum Choo

Summary: A novel nanoplasmonic substrate was developed for biomedical applications, which showed strong hot spots for detecting biomarkers at low concentrations. The substrate, called AuNPs@M13, was made by immobilizing 60 nm gold nanoparticles onto the surface of an M13 bacteriophage scaffold. It demonstrated higher sensitivity and lower limit of detection compared to commercially available assays.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Single-atom Cu-attached MOFs as peroxide-like enzymes to construct dual-mode immunosensors for detection of breast cancer typing in serum

Ning Li, Ya Zhang, Ying Xu, Xiaofang Liu, Jian Chen, Mei Yang, Changjun Hou, Danqun Huo

Summary: The molecular subtype of breast cancer guides treatment and drug selection. Invasive tests can promote cancer cell metastasis, so the development of high-performance, low-cost diagnostic tools for cancer prognosis is crucial. Liquid biopsy techniques enable noninvasive, real-time, dynamic, multicomponent, quantitative, and long-term observations at the cellular, genetic, and molecular levels. A Cu-Zr metal-organic framework (MOF) nanoenzyme with monatomic Cu attachment has been synthesized and proven to have high catalytic performance. The sensor constructed using this nanoenzyme shows potential for accurate classification of breast cancer serum samples.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Individually-addressable composite microneedle electrode array by mold-and-place method for glucose detection

Jeongmin Kim, Hyemin Kim, Seunghyun Park, Hyeonaug Hong, Yong Jae Kim, Jiyong Lee, Jaeho Kim, Seung-Woo Cho, Wonhyoung Ryu

Summary: This study presents a method to fabricate independently functioning microneedle (MN) electrodes with narrow intervals for high precision electrochemical sensing. The optimized mixture of photocurable polymer and single-wall carbon nanotubes was used to mold single composite MNs, which were then attached to pre-patterned electrodes. Plasma etching and electropolymerization were performed to enhance the electrochemical activity, and Prussian blue and glucose oxidase were electrodeposited on the MNs for glucose detection. The MN electrodes showed good sensitivity and linearity, and the feasibility of glucose detection was demonstrated in an in vivo mouse study.

SENSORS AND ACTUATORS B-CHEMICAL (2024)