Journal
SENSORS
Volume 10, Issue 12, Pages 11311-11321Publisher
MDPI
DOI: 10.3390/s101211311
Keywords
ferrocene; quinoxaline; mercury; electrochemistry; UV-vis spectroscopy
Funding
- MICINN-Spain [CTQ2008-01402]
- Fundacion Seneca (Agencia de Ciencia y Tecnologia de la Region de Murcia) [04509/GERM/06]
- Ministerio de Educacion de Espana
- European Union
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A new chemosensor molecule 3 based on a ferrocene-quinoxaline dyad recognizes mercury (II) cations in acetonitrile solution. Upon recognition, an anodic shift of the ferrocene/ferrocenium oxidation peaks and a progressive red-shift (Delta lambda = 140 nm) of the low-energy band, are observed in its absorption spectrum. This change in the absorption spectrum is accompanied by a colour change from orange to deep green, which can be used for a naked-eye detection of this metal cation.
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