4.7 Article

Viscoelastic properties of doped-ceria under reduced oxygen partial pressure

Journal

SCRIPTA MATERIALIA
Volume 75, Issue -, Pages 82-85

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.scriptamat.2013.11.027

Keywords

Ceramics; Sintering; Dynamic mechanical analysis; Powder consolidation

Funding

  1. EUDP (Danish Energy Agency) [64012-0225]

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The viscoelastic properties of gadolinium-doped ceria (CGO) powder compacts are characterized during sintering and cooling under reduced oxygen partial pressure and compared with conventional sintering in air. Under reducing conditions highly defective doped ceria shows peculiar viscoelastic properties due to fast mass diffusion phenomena activated at low temperatures by the reduction of Ce4+ to Ce3+. In particular, the viscous behavior is affected by dramatic microstructural changes, fast grain growth and densification, which are rapidly completed during the final stage of sintering. (C) 2013 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

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