Journal
SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS
Volume 13, Issue 6, Pages -Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1088/1468-6996/13/6/064216
Keywords
Ti-15Zr-4Nb-4Ta alloy; implantable metals; passive film; field-emission transmission electron microscopy; angle-resolved x-ray photoelectron spectroscopy; electrochemical stability evaluation
Categories
Funding
- Ministry of Economy, Trade, and Industry of Japan
Ask authors/readers for more resources
Metal release from implantable metals and the properties of oxide films formed on alloy surfaces were analyzed, focusing on the highly biocompatible Ti-15Zr-4Nb-4Ta alloy. The thickness and electrical resistance (R-p) of the oxide film on such an alloy were compared with those of other implantable metals. The quantity of metal released during a 1-week immersion test was considerably smaller for the Ti-15Zr-4Nb-4Ta than the Ti-6Al-4V alloy. The potential (E-10) indicating a current density of 10 mu A cm(-2) estimated from the anodic polarization curve was significantly higher for the Ti-15Zr-4Nb-4Ta than the Ti-6Al-4V alloy and other metals. Moreover, the oxide film (4-7 nm thickness) formed on the Ti-15Zr-4Nb-4Ta surface is electrochemically robust. The oxide film mainly consisted of TiO2 with small amounts of ZrO2, Nb2O5 and Ta2O5 that made the film electrochemically stable. The R-p of Ti-15Zr-4Nb-4Ta was higher than that of Ti-6Al-4V, i.e. 0.9 Omega cm(2) in 0.9% NaCl and 1.3 Omega cm(2) in Eagle's medium. This R-p was approximately five-fold higher than that of stainless steel, which has a history of more than 40 years of clinical use in the human body. Ti-15Zr-4Nb-4Ta is a potential implant material for long-term clinical use. Moreover, E-10 and R-p were found to be useful parameters for assessing biological safety.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available