Teaching an old carbocation new tricks: Intermolecular C–H insertion reactions of vinyl cations

Why Are Vinyl Cations Sluggish Electrophiles?

(2017) Peter A. Byrne et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Feedstocks to Pharmacophores: Cu-Catalyzed Oxidative Arylation of Inexpensive Alkylarenes Enabling Direct Access to Diarylalkanes

(2017) Aristidis Vasilopoulos et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Arylation of hydrocarbons enabled by organosilicon reagents and weakly coordinating anions

(2017) Brian Shao et al.   SCIENCE

Remote C–H insertion of vinyl cations leading to cyclopentenones

(2017) Sarah E. Cleary et al.   Chemical Science

Radical Desulfur-Fragmentation and Reconstruction of Enol Triflates: Facile Access to α-Trifluoromethyl Ketones

(2016) Xiaolong Su et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Reductive Cross-Coupling of Aryl Bromides with Alkyl Bromides: Et3N as the Terminal Reductant

(2016) Zhengli Duan et al.   ORGANIC LETTERS

Electrophilic Fluorophosphonium Cations in Frustrated Lewis Pair Hydrogen Activation and Catalytic Hydrogenation of Olefins

(2015) Thorsten vom Stein et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

B(C6F5)3-Catalyzed Transfer of Dihydrogen from One Unsaturated Hydrocarbon to Another

(2015) Indranil Chatterjee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Cyclic Alkenyl Triflates by a Cationic Cyclization Reaction and its Application in Biomimetic Polycyclizations and Synthesis of Terpenes

(2015) Pedro Alonso et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Scope and Mechanistic Analysis for Chemoselective Hydrogenolysis of Carbonyl Compounds Catalyzed by a Cationic Ruthenium Hydride Complex with a Tunable Phenol Ligand

(2015) Nishantha Kalutharage et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transannular [6 + 4] and Ambimodal Cycloaddition in the Biosynthesis of Heronamide A

(2015) Peiyuan Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ene-hydrazide from Enol Triflate for the Regioselective Fischer Indole Synthesis

(2014) Byeong-Yun Lim et al.   ORGANIC LETTERS

Copper-Catalyzed Carboarylation of Alkynes via Vinyl Cations

(2013) Andrew J. Walkinshaw et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

H+, CH3+, and R3Si+Carborane Reagents: When Triflates Fail

(2009) Christopher A. Reed   ACCOUNTS OF CHEMICAL RESEARCH

A potential energy surface bifurcation in terpene biosynthesis

(2009) Young J. Hong et al.   Nature Chemistry

Bifurcations on Potential Energy Surfaces of Organic Reactions

(2008) Daniel H. Ess et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION