4.1 Article

Composite electrodes of electrochemical capacitors based on carbon materials with different structure

Journal

RUSSIAN JOURNAL OF ELECTROCHEMISTRY
Volume 50, Issue 5, Pages 419-428

Publisher

MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1023193514050097

Keywords

electrochemical capacitor; active carbon; composite electrode; electric double layer; mesostructure

Funding

  1. Russian Foundation for Basic Research [11-03-00610-a]
  2. Ministry of Education and Science of Russia [675]

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For composite electrodes based on active carbon DCL Supra 30, ordered mesoporous carbon, and synthetic carbon material Sibunit, the electrical double layer capacitance is studied. The original carbon samples are characterized by the methods of gas adsorption, X-ray diffraction, and transmission electron microscopy. The mesoporous structure of the material synthesized by the template method provides the maximum rate of ion transport in pores and demonstrates an insignificant decrease in the specific capacitance (9.5% in an aqueous electrolyte and 1.1% in an nonaqueous electrolyte) with an increase in the polarizing current.

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