4.1 Article

Synthesis of new acids based on bis(dicarbollide)cobalt

Journal

RUSSIAN CHEMICAL BULLETIN
Volume 63, Issue 10, Pages 2334-2337

Publisher

SPRINGER
DOI: 10.1007/s11172-014-0743-z

Keywords

bis(dicarbollide)cobalt; cyclic oxonium derivatives; acids; boron neutron capture therapy of cancer

Funding

  1. Russian Foundation for Basic Research [12-03-00772, 13-03-00581]
  2. Russian Academy of Sciences (Program of the Presidium of the Russian Academy of Sciences Development of Methods for Preparation of Chemical Compounds and Development of New Materials) [P-8]

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New acids based on bis(dicarbollide)cobalt [8-HOOC(CH2) (n) NH2(CH2CH2O)(2)-3,3'-Co(1,2-C2B9H10)(1',2'-C2B9H11)] (n = 1, 3) were obtained by the reaction of its 1,4-dioxane derivative with omega-amino acid esters and subsequent removal of the protection.

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