Journal
RUSSIAN CHEMICAL BULLETIN
Volume 62, Issue 7, Pages 1493-1502Publisher
SPRINGER
DOI: 10.1007/s11172-013-0213-z
Keywords
lignocellulosic biomass; oxidative and acid-catalyzed conversions; solid catalysts; cellulose; glucose; levulinic acid; fuel additives
Categories
Funding
- Russian Foundation for Basic Research [12-03-93117-NtsNIL]
- Federal Target Program Research and Development in Priority Areas of the Scientific-Technological Complex of Russia [14.516.11.0071]
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This review deals with the use of solid catalysts for the enhancement of the efficiency and the development of a new generation of environmentally friendly, energy and resource efficient processes for the deep processing of lignocellulosic biomass to desired chemicals. The oxidative delignification of wood with hydrogen peroxide in the presence of the suspended TiO2 catalyst, the oxidation of wood with molecular oxygen in the presence of copper catalysts, the acidcatalyzed conversion of cellulose to glucose and levulinic acid, and the thermal conversion of lignin to fuel additives on solid acid catalysts are analyzed. New integrated processes based on the heterogeneous catalytic oxidation are suitable for the complex processing of lignocellulosic biomass to produce valuable chemicals and engine fuel components without the use of toxic and corrosion-active reagents.
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