Journal
RUSSIAN CHEMICAL BULLETIN
Volume 62, Issue 2, Pages 548-553Publisher
SPRINGER
DOI: 10.1007/s11172-013-0076-3
Keywords
binuclear cobalt-copper carborane clusters; synthesis; dynamic behavior in solution; crystal structure
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Funding
- Russian Foundation for Basic Research [12-03-00102]
- Russian Academy of Sciences [P-8]
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Zwitterionic 4,8,8'-exo-{Ph3PCu}-4,8,8'-(mu-H)(3)-commo-3,3'-Co(1,2-C2B9H9)-(1',2'-C2B9H10) and ionic [(PPh3)(3)Cu][commo-3,3'-Co(1,2-C2B9H11)(2) complexes were synthesized in moderate yields by the reaction of anionic commo-complex [Cs][commo-3,3'-Co-(1,2-C2B9H11)(2)]) in a CH2Cl2 solution with anhydrous CuCl2 or CuCl in the presence of PPh3. The complexes were also synthesized by alternative methods and characterized by NMR and X-ray diffraction methods.
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