Journal
RUSSIAN CHEMICAL BULLETIN
Volume 61, Issue 10, Pages 1943-1949Publisher
SPRINGER
DOI: 10.1007/s11172-012-0269-1
Keywords
organomagnesium compounds; metal complex catalysis; magnesacyclopentane; 1,2-dienes; 1Z,5Z-dienes; cyclomagnesiation
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Funding
- Russian Foundation for Basic Research [10-03-00046, 11-03-00103, 11-03-97001]
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A Cp2TiCl2-catalyzed intermolecular homocyclomagnesiation of O-containing 1,2-dienes and cross-cyclomagnesiation of O-containing 1,2-dienes with aliphatic 1,2-dienes of cyclic and acyclic structure have been accomplished using Grignard reagents, which led to mono- and bicyclic organomagnesium compounds in 61-94% yields.
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