Journal
RUSSIAN CHEMICAL BULLETIN
Volume 59, Issue 8, Pages 1665-1667Publisher
SPRINGER
DOI: 10.1007/s11172-010-0292-z
Keywords
carboranes; cross-coupling; phenylboronic acid; aryl halides; phosphites
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Isomeric carborane-containing phosphite ligands possessing different electronic properties have been synthesized. Their use in the Pd-catalyzed Suzuki-Miyaura reaction involving activated aryl bromides showed that phosphite with 9-o-carborane substituent has proved more efficient, with carboranyl phosphite having 1-m- carborane fragment being more efficient in the reactions with nonactivated aryl bromides.
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