Journal
RUSSIAN CHEMICAL BULLETIN
Volume 59, Issue 4, Pages 741-744Publisher
SPRINGER
DOI: 10.1007/s11172-010-0155-7
Keywords
chromium terephthalate; molybdenum clusters; rhenium clusters; coordination polymers; mesoporous structures; luminescence
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Funding
- Russian Foundation for Basic Research [07-03-00436, 08-03-12007]
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The luminescence properties of mesoporous chromium(III) terephthalate [Cr3O(C8H4O4)(3)F(H2O)(2)] (MIL-101) were discovered, and the luminescence spectra were detected at temperatures from 20 to 290 K. By the interaction of MIL-101 with solutions of anionic clusters [Mo6Cl14](2-) (Mo-6) and [Re6S8(CN)(6)](4-) (Re-6) new hybrid materials Mo6MIL-101 and Re6MIL-101 were synthesized, the nanoporous framework of which contains (ca). 3.5 and 1.5 clusters per cage, respectively. The synthesized hybrid materials possess the luminescence properties different from those of the initial framework and cluster complexes.
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