Journal
RUSSIAN CHEMICAL BULLETIN
Volume 59, Issue 3, Pages 556-559Publisher
SPRINGER
DOI: 10.1007/s11172-010-0125-0
Keywords
boron hydrides; closo-decaborate; ring opening; derivatives with terminal sulfur-containing group
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Funding
- Council on Grants of the President of the Russian Federation [NSh-1518.2008.3]
- Russian Foundation for Basic Research [07-03-00552]
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The reaction of the [B10H9O2C4H8](-), [B10H9OC4H8](-), and [(BHOCH10)-H-10-O-9-H-5](-) anions with negatively charged S-nucleophiles, such as SH-, SCN-, and S2O32-, resulted in the ring opening of the cyclic substituent and the formation of derivatives with the terminal thiol, thiocyanate, and thiosulfate groups. The structures of the products were confirmed by the IR, mass, and H-1, B-11, and C-13 NMR spectra.
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