4.1 Article

Nonsymmetrical iron bis(carborane) complexes (η-1-ButNH-1,7,9-C3B8H10)Fe(η-9-L-7,8-C2B9H10) (L = SMe2, NMe3)

Journal

RUSSIAN CHEMICAL BULLETIN
Volume 59, Issue 11, Pages 2143-2146

Publisher

SPRINGER
DOI: 10.1007/s11172-010-0370-2

Keywords

iron; metallacarboranes; sandwich compounds

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Visible light irradiation of the benzene complex [(eta-1-(BuNH)-N-t-1,7,9-C3B8H10)Fe(eta-C6H6)](+) in the presence of the charge-compensated carborane anions [9-L-7,8-C2B9H10](-) (L = SMe2, NMe3) affords ferracarboranes (eta-1-(BuNH)-N-t-1,7,9-C3B8H10)Fe(eta-9-L-7,8-C2B9H10). Their structures were established by X-ray diffraction analysis.

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