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Design of supramolecular metal complex catalytic systems for petrochemical and organic synthesis

Journal

RUSSIAN CHEMICAL BULLETIN
Volume 57, Issue 4, Pages 780-792

Publisher

SPRINGER
DOI: 10.1007/s11172-008-0117-5

Keywords

supramolecular catalytic systems; molecular imprinting; cyclodextrins; calixarenes; dendrimers; host-guest complexes; hydroformylation; Wacker oxidation; aromatics coupling; rhodium complexes; palladium complexes

Funding

  1. Russian Foundation for Basic Research [06-03-32889a, 07-03-00221]

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Specific features of the behavior of the supramolecular metal complex catalysts based on calixarenes, cyclodextrins, and dendrimers in the reactions of hydroformylation, Wacker oxidation, hydroxylation of aromatics, 2-naphthol coupling, and oxidative coupling of styrenes and benzene were studied. The factors affecting the catalytic activity and selectivity are discussed.

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