4.1 Article

Synthesis of new building blocks based on the closo-dodecaborate anion

Journal

RUSSIAN CHEMICAL BULLETIN
Volume 57, Issue 9, Pages 1996-1998

Publisher

SPRINGER
DOI: 10.1007/s11172-008-0268-4

Keywords

closo-dodecaborate; oxonium derivatives; aldehydes; carboxylic acids; building blocks

Funding

  1. Russian Foundation for Basic Research [08-03-00463-a, 08-03-91951-NNIO-a]

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The reactions of the dioxonium derivative of closo-dodecaborate(12) with aromatic aldehydes and esters containing O- and N-nucleophilic centers were studied. These reactions were used to synthesize new closo-dodecaborate-based building blocks containing aldehyde and acidic groups.

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