4.1 Article

Phosphorus derivatives of carboranes as ligands for Pd-catalyzed cross-coupling reactions

Journal

RUSSIAN CHEMICAL BULLETIN
Volume 57, Issue 11, Pages 2307-2310

Publisher

SPRINGER
DOI: 10.1007/s11172-008-0326-y

Keywords

carboranes; cross-coupling; phenylboronic acid; aryl halides; phosphines; phosphites

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Carborane-containing phosphine ligands having different steric and electronic properties were synthesized. Testing of these ligands in the Pd-catalyzed Suzuki-Miyaura reaction showed higher catalytic activity for sterically congested phosphine ligands with acceptor carborane substituents.

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