4.5 Article

Cryogenic implementation of charging diamond anvil cells with H2 and D2

Journal

REVIEW OF SCIENTIFIC INSTRUMENTS
Volume 82, Issue 10, Pages -

Publisher

AMER INST PHYSICS
DOI: 10.1063/1.3652981

Keywords

cryogenics; fluorescence spectroscopy; optical microscopes

Funding

  1. New Energy Development Organization (NEDO) under Advanced Fundamental Research on Hydrogen Storage Materials
  2. Grants-in-Aid for Scientific Research [22000002] Funding Source: KAKEN

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A cryogenic loading system for introducing H-2 and D-2 into the diamond anvil cell has been designed and constructed. The integration of pressure loading mechanism, ruby fluorescence spectrometer, and microscope camera allows for in situ tuning and calibrating the pressure. The performance of the system has been demonstrated by successful synthesis of hydride and deuteride of transition metal and rare earth metal. Our cryogenic methodology features facile start-over of loading and in situ electrical resistance measurement of as-synthesized sample. (C) 2011 American Institute of Physics. [doi:10.1063/1.3652981]

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