4.5 Article

Near-infrared photon time-of-flight spectroscopy of turbid materials up to 1400 nm

Journal

REVIEW OF SCIENTIFIC INSTRUMENTS
Volume 80, Issue 6, Pages -

Publisher

AMER INST PHYSICS
DOI: 10.1063/1.3156047

Keywords

acousto-optical filters; gallium arsenide; gallium compounds; III-V semiconductors; indium compounds; infrared spectroscopy; measurement by laser beam; microchannel plates; photomultipliers; polymers; spectrochemical analysis; time of flight spectroscopy; turbidity

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Photon time-of-flight spectroscopy (PTOFS) is a powerful tool for analysis of turbid materials. We have constructed a time-of-flight spectrometer based on a supercontinuum fiber laser, acousto-optical tunable filtering, and an InP/InGaAsP microchannel plate photomultiplier tube. The system is capable of performing PTOFS up to 1400 nm, and thus covers an important region for vibrational spectroscopy of solid samples. The development significantly increases the applicability of PTOFS for analysis of chemical content and physical properties of turbid media. The great value of the proposed approach is illustrated by revealing the distinct absorption features of turbid epoxy resin. Promising future applications of the approach are discussed, including quantitative assessment of pharmaceuticals, powder analysis, and calibration-free near-infrared spectroscopy.

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