4.5 Article

Photocatalytic conversion of CO2 into value-added hydrocarbon (methanol) with high selectivity over ZnS nanoparticles driven by 355-nm pulsed laser

Journal

RESEARCH ON CHEMICAL INTERMEDIATES
Volume 41, Issue 2, Pages 739-747

Publisher

SPRINGER
DOI: 10.1007/s11164-013-1224-y

Keywords

ZnS; CO2 conversion; Photocatalytic; 355-nm pulsed laser; Methanol

Funding

  1. National Natural Science Foundation of China [51172109]
  2. Jiangsu Province Natural Science Foundation [BK2010497]
  3. Deanship of Scientific Research, King Fahd University of Petroleum and Minerals [RG1011-1]

Ask authors/readers for more resources

In the present investigation, monochromatic 355-nm pulsed laser radiations generated by third harmonic of Nd:YAG laser (1,060 nm) were applied as an excitation light source for conversion of CO2 into value-added hydrocarbon (methanol) with high selectivity over ZnS particles through photo-catalytic process. The microstructure and optical band absorption of as-prepared ZnS nanoparticles were characterized by means of XRD, UV-Vis absorption spectrum, TEM, SAED, and EDX spectrum. The effect of irradiation time as well as the pulsed laser energy on methanol yield and photoefficiency were investigated and discussed in detail. Furthermore, a possible mechanism for such conversion process is also discussed based on the band edge of ZnS semiconductor and the unique monochromatic characteristic of the adopted 355-nm pulsed laser.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.5
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Materials Science, Ceramics

Structural parameters, energy states and magnetic properties of the novel Se-doped NiFe2O4 ferrites as highly efficient electrocatalysts for HER

Muhammad Hassan, Yassine Slimani, Mohammed A. Gondal, Mohamed J. S. Mohamed, Sadik Guener, Munirah A. Almessiere, Aroob M. Surrati, Abdulhadi Baykal, Sergei Trukhanov, Alex Trukhanov

Summary: This study focuses on the production and investigation of NiFe2O4 spinel ferrite nanoparticles doped with different masses of Se. The results show that the chemical content of Se has an impact on the crystal structure, microstructure, and magnetic properties. Superparamagnetic and ferrimagnetic states are observed in a wide magnetic field range. The magnetic characteristics do not change significantly when Se-substitution is less than 2.0%. However, a nonlinear dependence of magnetic parameters is observed for samples with Se-substitution greater than or equal to 2.0%. The undoped sample and NiFe2O4+x%Se exhibit soft magnetic behavior.

CERAMICS INTERNATIONAL (2022)

Article Energy & Fuels

Metal-organic framework coordinated with cobalt ion as charge recombination retarder in dye-sensitized solar cells

Muhammad Younas, Mohammed Ashraf Gondal, Mohamed A. Dastageer, Aasif Hilal

Summary: In this study, a layer of cobalt-metallic-ion-coordinated metal-organic framework (Co-MOF199) is deposited on the photoanode of conventional dye-sensitized solar cell (DSSC), resulting in increased electron recombination lifetime and resistance, leading to improved open-circuit voltage and power conversion efficiency.

INTERNATIONAL JOURNAL OF ENERGY RESEARCH (2022)

Article Materials Science, Multidisciplinary

Metamaterial electromagnetic wave absorbers and devices: Design and 3D microarchitecture

Qianqian Huang, Gehuan Wang, Ming Zhou, Jing Zheng, Shaolong Tang, Guangbin Ji

Summary: Metamaterials are artificial composite structures with supernormal physical properties that allow effective manipulation of electromagnetic waves. One important application is metamaterial absorbers, which achieve perfect absorption through reasonable design. This review focuses on bionic design, new artificial design, and the use of 3D printing technology to prepare metamaterial absorbers.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2022)

Article Chemistry, Physical

Self-templated anchor of FeS2 nanoparticles on porous carbon matrix as highly reversible K-storage anode

Nailu Shen, Ningning Chen, Yinshuang Pang, Shenluo Zang, Chi Hu, Zeming Tang, Qingxue Lai, Jing Zheng, Yanyu Liang

Summary: In this study, FeS2 nanoparticles were anchored on N-doped porous carbon to enhance the capacity and cycle stability of potassium-ion batteries. The findings provide a foundation for designing high-performance Fe-based anodes for PIBs.

APPLIED SURFACE SCIENCE (2023)

Article Chemistry, Physical

Synthesis of Ce and Sm Co-Doped TiO2 Nanoparticles with Enhanced Photocatalytic Activity for Rhodamine B Dye Degradation

Yassine Slimani, Munirah A. Almessiere, Mohamed J. S. Mohamed, Essia Hannachi, Serkan Caliskan, Sultan Akhtar, Abdulhadi Baykal, Mohammed A. Gondal

Summary: One of the major concerns globally is the presence of organic pollutants in wastewater and water resources, specifically Rhodamine B, which is highly persistent and toxic. Metal oxide semiconducting materials, such as TiO2, have been studied for their ability to remove organic pollutants. In this study, a series of Ce-Sm co-doped TiO2 nanoparticles were prepared and their photocatalytic activity was evaluated. It was found that all co-doped nanoparticles showed better photocatalytic activity than pristine TiO2, with the x = 0.50% sample demonstrating the highest degradation efficiency.

CATALYSTS (2023)

Article Immunology

Multicenter, single-arm, phase II study (CAP) of radiotherapy plus liposomal irinotecan followed by camrelizumab and anti-angiogenic treatment in advanced solid tumors

Jie Shen, Jing Yan, Juan Du, Xiaoqin Li, Jia Wei, Qin Liu, Hongmei Yong, Xiaolu Wang, Xiaofeng Chang, Zhou Ding, Wu Sun, Chenxi Liu, Sihui Zhu, Jingyi Guo, Huajun Li, Ying Liu, Wulou Zhang, Zonghang Liu, Rutian Li, Baorui Liu

Summary: This study conducted a clinical trial on advanced solid tumor patients using a combination therapeutic mode. The results showed that the combination of radiotherapy, liposomal irinotecan, camrelizumab, and anti-angiogenesis therapy demonstrated promising anti-tumor activity and well tolerance in various advanced solid tumors.

FRONTIERS IN IMMUNOLOGY (2023)

Article Chemistry, Multidisciplinary

Preparation and Characterization of Physically Activated Carbon and Its Energetic Application for All-Solid-State Supercapacitors: A Case Study

Aziz Ahmad, Mohammed Ashraf Gondal, Muhammad Hassan, Rashid Iqbal, Sami Ullah, Atif Saeed Alzahrani, Waqar Ali Memon, Fazal Mabood, Saad Melhi

Summary: Biomass-derived physically activated carbon was obtained from date seed biomass as symmetric electrodes for all-solid-state supercapacitors (SCs). PVA/KOH gel polymer electrolyte was used in the SCs. The C-850 electrode showed the best electrochemical performances, with a specific capacitance of 138.12 F g(-1) at 5 mV s(-1) and an energy density of 9.6 Wh kg(-1).

ACS OMEGA (2023)

Article Nanoscience & Nanotechnology

Se-Doped Magnetic Co-Ni Spinel Ferrite Nanoparticles as Electrochemical Catalysts for Hydrogen Evolution

Mohamed Jaffer Sadiq Mohamed, Serkan Caliskan, Mohammed Ashraf Gondal, Munirah Abdullah Almessiere, Abdulhadi Baykal, Yassine Slimani, Khaled Abdelsabour Elsayed, Muhammad Hassan, Ismail Abdullah Auwal, Abdul Zeeshan Khan, Asif Ali Tahir, Anurag Roy

Summary: The magnetic properties of Co0.5Ni0.5Fe2O4 spinel ferrites can be tuned by Se doping, with increased coercivity and remanence at 10 K. An optimized catalyst, CoNi NSFs + 0.15% Se, exhibits superior electrocatalytic performance for the hydrogen evolution reaction (HER), with a low overpotential and high stability. This research is important for developing hard magnetic materials and efficient electrocatalysts for sustainable energy generation.

ACS APPLIED NANO MATERIALS (2023)

Article Materials Science, Multidisciplinary

High electrochemical energy storage device via cation insertion kinetics in Cs3Bi2(Cl0.5I0.5)(9)@NiO composite electrodes with wide potential window

Luqman E. Oloore, Mohammed A. Gondal, Idris K. Popoola, AbdulJelili Popoola

Summary: Pseudocapacitive materials usually have low capacitance and conductivity, but the designed perovskite electrode architecture in this study improves ion accessibility and provides high gravimetric and area normalized capacitance.

MATERIALS CHEMISTRY AND PHYSICS (2023)

Article Chemistry, Multidisciplinary

Effective Hydrogen Production from Alkaline and Natural Seawater using WO3 (-x )@CdS1-x Nanocomposite-Based Electrocatalysts

Mohamed Jaffer Sadiq Mohamed, Mohammed Ashraf Gondal, Muhammad Hassan, Munirah Abdullah Almessiere, Asif Ali Tahir, Anurag Roy

Summary: Offshore hydrogen production through water electrolysis presents significant challenges, but the use of WCSNCs catalysts can enhance the efficiency of the hydrogen evolution reaction, especially in alkaline and natural seawater environments.

ACS OMEGA (2023)

Article Chemistry, Multidisciplinary

Investigating the Soil Unconfined Compressive Strength Based on Laser-Induced Breakdown Spectroscopy Emission Intensities and Machine Learning Techniques

Yakubu Sani Wudil, Osama Atef Al-Najjar, Mohammed A. A. Al-Osta, Omar Baghabra S. Al-Amoudi, Mohammed Ashraf Gondal

Summary: Laser-induced breakdown spectroscopy (LIBS) is a significant technique for elemental identification and quantification. In this study, a novel technique using artificial intelligence is developed to estimate the soil unconfined compressive strength based on LIBS spectra. The models demonstrate good prediction capability and applicability, as confirmed by evaluation and validation.

ACS OMEGA (2023)

Article Multidisciplinary Sciences

Copper Nanoparticles Doped on Polyvinyl Alcohol/Polymethyl Methacrylate/Montmorillonite (PVA-PMMA/MMT) as Ecofriendly Polymeric Hybrid Clay Composites: Study of their Bactericidal and Physical Properties

Sabiha Sultana, Mohammed A. Gondal, Amir Naveed, Imran Rehan, Kamran Rehan, Noor Ul Amin, Luqman Ali Shah, Shah Khalid, Bassam El Ali, M. A. Almessiere

Summary: This paper presents the synthesis, physical characterization, and antibacterial properties of copper nanoparticles (CuNPs) incorporated in activated PVA/PMMA/montmorillonite (MMT) polymeric clay composites. The CuNPs were prepared using an eco-friendly solvent evaporation technique. The UV-Vis spectral analysis showed that the optical band gap energy of the composites could be adjusted by controlling the CuNPs loading, making them suitable for optoelectronic applications. XRD analysis confirmed a strong interaction between CuNPs and the polymeric clay composite. The composites exhibited improved hydrophobicity and excellent bactericidal activity, suggesting their potential use in the food packaging industry.

ARABIAN JOURNAL FOR SCIENCE AND ENGINEERING (2023)

Article Multidisciplinary Sciences

Non-invasive Diabetes Mellitus Diagnostics Using Laser-Induced Breakdown Spectroscopy and Support Vector Machine Algorithm

Imran Rehan, Saranjam Khan, M. A. Gondal, Qamar Abbas, Rahat Ullah

Summary: This study uses SVM algorithm and LIBS technology to identify diabetes mellitus in human urine. By collecting pathological urine samples from diabetic patients and control samples from non-diabetic individuals, LIBS spectra of both groups were obtained and analyzed using PCA and support vector classifier. SVM models with various kernel functions were developed and evaluated using k-fold cross-validation, and the radial basis function (RBF) kernel demonstrated the highest performance efficiency. The results highlight the potential of LIBS approach for real-time assessment of diabetes mellitus in clinical trials.

ARABIAN JOURNAL FOR SCIENCE AND ENGINEERING (2023)

Article Multidisciplinary Sciences

Preparation of Agro Waste Derived Poly Lactic Acid Based Green Renewable Nanocomposites with Improved Morphological, Enhanced Thermal, Mechanical and Augmented Antimicrobial Performance

Sabiha Sultana, Mohammed A. Gondal, Muhammad Haris, Imran Rehan, Kamran Rehan, Saqib Khan, Muhammad Saleem

Summary: In this study, silica powder was successfully prepared from raw rice husk and silver nanoparticles were synthesized using natural neem leaves. Biodegradable nanocomposites were fabricated by blending polylactic acid, silver nanoparticles, montmorillonite MMT and silica with filler contents. The incorporation of silica improved the mechanical properties and thermal stability of the nanocomposites, and inhibited bacterial growth.

ARABIAN JOURNAL FOR SCIENCE AND ENGINEERING (2023)

Review Nanoscience & Nanotechnology

A Novel Strategy in Electromagnetic Wave Absorbing and Shielding Materials Design: Multi-Responsive Field Effect

Yue Zhao, Lele Hao, Xindan Zhang, Shujuan Tan, Haohang Li, Jing Zheng, Guangbin Ji

Summary: The use of electromagnetic (EM) devices has become widespread in various fields, but it also brings about issues such as signal pollution and radiation. To tackle these problems, researchers have been working on developing electromagnetic wave absorbing and shielding (EMAS) materials. However, most of the reported materials only possess the EMAS property. In practical applications, materials with excellent tunable absorption bands are needed. This review focuses on different external field-responsive materials and provides a detailed summary of various action mechanisms, materials synthesis methods, and macrostructures. The future trends in developing novel external field-responsive materials are also discussed.

SMALL SCIENCE (2022)

No Data Available