4.1 Article

EVALUATION OF OXIDATION STABILITY OF SUNFLOWER OIL BIODIESEL WITH ANTIOXIDANTS

Journal

QUIMICA NOVA
Volume 32, Issue 1, Pages 106-111

Publisher

SOC BRASILEIRA QUIMICA
DOI: 10.1590/S0100-40422009000100020

Keywords

energy; peroxidation; lipid oxidation

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Biodiesel can contain unsaturated fatty acids, which are susceptible to oxidation, being able to change into polymerized compounds. In this work biodiesel was characterized according to physical-chemistry parameters and the antioxidant activity of butylated hydroxyanisole (BHA), butylated hydroxytoluene (BHT) and tert-butylhydroquinone (TBHQ) added to biofuel was analyzed. Biodiesel was submitted to accelerate oxidation in the Schaal oven test, and peroxide value was analyzed. The absorptivity values at 232 nm and 270 nm and oxidative stability in Rancimat (R) were determined. It was observed that TBHQ presented superior antioxidant activity than BHT and BHA.

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