4.1 Article

Electrochemical behavior of parent and photodegradation products of some selected pesticides

Journal

QUIMICA NOVA
Volume 31, Issue 6, Pages 1310-1314

Publisher

SOC BRASILEIRA QUIMICA
DOI: 10.1590/S0100-40422008000600007

Keywords

pesticides; differential pulse voltammetry; photodegradation

Funding

  1. FAPESP
  2. EMBRAPA
  3. CAPES [01/13745-7]
  4. CNPq [310750/2006-7]

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Electrochemical behavior of pesticides is extensively studied, but little attention has been given to the Study of their degradation products (by-products) by electrochemical methods. However, the degradation products of pesticides can be even more toxic then the parent products and such studies should be encouraged. Therefore. the objective of this work was to evaluate the electroactivity of by-products of imazaquin. methylparathion. bentazon and atrazine. generated by UV irradiation and measured using cyclic and differential Pulse voltammetry and UV visible absorption spectrophotometry. Results have shown that several by-products exhibit electroactivity, allowing, in some cases. the simultaneous determination of both parent and degradation products.

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