Journal
PURE AND APPLIED CHEMISTRY
Volume 81, Issue 8, Pages 1473-1488Publisher
WALTER DE GRUYTER GMBH
DOI: 10.1351/PAC-CON-08-08-36
Keywords
ionic liquids; liquid-liquid interfaces; two-phase liquid systems; ion transfer; electron transfer; standard Gibbs energy of ion transfer; polarized potential window
Categories
Funding
- Ministry of Education, Youth and Sports of the Czech Republic [KONTAKT/ME08098]
- Grant Agency of the Academy of Sciences of the Czech Republic [IAA400400704]
- Scientific Research [18350006]
- Priority Area [20031017]
- Global COE program International Center for Integrated Research and Advanced Education in Materials Science [B-09]
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This article provides a brief review of theoretical and methodological concepts in the area of the charge-transfer processes at the interface between a hydrophobic ionic liquid (IL) and an electrolyte solution in water (W). Electrochemical methods of study of the W|IL interfaces are described, current experimental problems are indicated, and the most important experimental results are summarized. The relevance of electrochemistry at the W|IL interfaces to the extraction behavior of ILs is outlined.
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